{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/124729"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/124729","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Preliminary framework for quantitative sustainable design of redox-mediated electrodialysis for biorefinery separations","abstract":"Electrodialysis (ED) is an electrochemical unit operation that may help advance the production of bio-based organic acids, including succinic acid. Redox-ED is one particular class of electrochemical technology that can contain novel layer-by-layer (LBL) membranes and employ a modified cell pair and redox-flow platform. Environmental and chemical engineering industries are gaining interested in modeling redox-ED as it possible that modern advances in the novel layer-by-layer membrane technology can be economically and environmentally feasible when implemented in the downstream separations of fermentation-based processes. This work couples an empirical model of technology performance with a framework for quantitative sustainable design of downstream redox-ED and will provide a way to define the opportunity space for this novel technology. Findings include a baseline levelized cost estimation of 5.76 USD∙kg SA-1 and technology targets for achieving a levelized cost of 1.19 USD∙kg SA-1 with advances in flux of succinic acid (SA) and specific energy consumption. In coupling an empirical model with a quantitative sustainable design framework, this work aims to give a sense for the feasibility of redox-ED implementation at an industrially relevant scale to prioritize future research directions by characterizing economic and environmental indicators for sustainability.","abstract_html":"Electrodialysis (ED) is an electrochemical unit operation that may help advance the production of bio-based organic acids, including succinic acid. Redox-ED is one particular class of electrochemical technology that can contain novel layer-by-layer (LBL) membranes and employ a modified cell pair and redox-flow platform. Environmental and chemical engineering industries are gaining interested in modeling redox-ED as it possible that modern advances in the novel layer-by-layer membrane technology can be economically and environmentally feasible when implemented in the downstream separations of fermentation-based processes. This work couples an empirical model of technology performance with a framework for quantitative sustainable design of downstream redox-ED and will provide a way to define the opportunity space for this novel technology. Findings include a baseline levelized cost estimation of 5.76 USD∙kg SA-1 and technology targets for achieving a levelized cost of 1.19 USD∙kg SA-1 with advances in flux of succinic acid (SA) and specific energy consumption. In coupling an empirical model with a quantitative sustainable design framework, this work aims to give a sense for the feasibility of redox-ED implementation at an industrially relevant scale to prioritize future research directions by characterizing economic and environmental indicators for sustainability.","abstract_has_math":false,"creators":["Allen, Jayne Louise"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"M.S.","degree_level":"Thesis","degree_discipline":"Environ Engr in Civil Engr","degree_department":null,"school":null,"contributors":["Guest, Jeremy S"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2024,"date_issued":"2024-05-03","date_published":"2024-05-03","updated_at":"2026-07-22T22:25:02Z","subjects":["Technoeconomic Analysis","Life Cycle Assessment","Redox-mediated Electrodialysis Downstream Separations","Organic Acid Upconcentration"],"languages":["eng","en"],"rights":["Copyright 2024 Jayne Allen"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/124729","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Guest, Jeremy S"]},{"key":"dc:creator","label":"Author","values":["Allen, Jayne Louise"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2024-05-03","2024-05"]},{"key":"dc:type","label":"Dc Type","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Environ Engr in Civil Engr"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.S."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Technoeconomic Analysis","Life Cycle Assessment","Redox-mediated Electrodialysis Downstream Separations","Organic Acid Upconcentration"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng","en"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2024 Jayne Allen"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/124729"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Electrodialysis (ED) is an electrochemical unit operation that may help advance the production of bio-based organic acids, including succinic acid. Redox-ED is one particular class of electrochemical technology that can contain novel layer-by-layer (LBL) membranes and employ a modified cell pair and redox-flow platform. Environmental and chemical engineering industries are gaining interested in modeling redox-ED as it possible that modern advances in the novel layer-by-layer membrane technology can be economically and environmentally feasible when implemented in the downstream separations of fermentation-based processes. This work couples an empirical model of technology performance with a framework for quantitative sustainable design of downstream redox-ED and will provide a way to define the opportunity space for this novel technology. Findings include a baseline levelized cost estimation of 5.76 USD∙kg SA-1 and technology targets for achieving a levelized cost of 1.19 USD∙kg SA-1 with advances in flux of succinic acid (SA) and specific energy consumption. In coupling an empirical model with a quantitative sustainable design framework, this work aims to give a sense for the feasibility of redox-ED implementation at an industrially relevant scale to prioritize future research directions by characterizing economic and environmental indicators for sustainability.","Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-05-01","The student, Jayne Allen, accepted the attached license on 2024-05-03 at 14:41.","The student, Jayne Allen, submitted this Thesis for approval on 2024-05-03 at 14:52.","This Thesis was approved for publication on 2024-05-03 at 15:08.","DSpace SAF Submission Ingestion Package generated from Vireo submission #20778 on 2024-09-16 at 00:51:18"]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Preliminary framework for quantitative sustainable design of redox-mediated electrodialysis for biorefinery separations"]}]}],"canonical_facts":{"dc:contributor":["Guest, Jeremy S"],"dc:creator":["Allen, Jayne Louise"],"dc:date":["2024-05-03","2024-05"],"dc:description":["Electrodialysis (ED) is an electrochemical unit operation that may help advance the production of bio-based organic acids, including succinic acid. Redox-ED is one particular class of electrochemical technology that can contain novel layer-by-layer (LBL) membranes and employ a modified cell pair and redox-flow platform. Environmental and chemical engineering industries are gaining interested in modeling redox-ED as it possible that modern advances in the novel layer-by-layer membrane technology can be economically and environmentally feasible when implemented in the downstream separations of fermentation-based processes. This work couples an empirical model of technology performance with a framework for quantitative sustainable design of downstream redox-ED and will provide a way to define the opportunity space for this novel technology. Findings include a baseline levelized cost estimation of 5.76 USD∙kg SA-1 and technology targets for achieving a levelized cost of 1.19 USD∙kg SA-1 with advances in flux of succinic acid (SA) and specific energy consumption. In coupling an empirical model with a quantitative sustainable design framework, this work aims to give a sense for the feasibility of redox-ED implementation at an industrially relevant scale to prioritize future research directions by characterizing economic and environmental indicators for sustainability.","Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-05-01","The student, Jayne Allen, accepted the attached license on 2024-05-03 at 14:41.","The student, Jayne Allen, submitted this Thesis for approval on 2024-05-03 at 14:52.","This Thesis was approved for publication on 2024-05-03 at 15:08.","DSpace SAF Submission Ingestion Package generated from Vireo submission #20778 on 2024-09-16 at 00:51:18"],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/124729"],"dc:language":["eng","en"],"dc:rights":["Copyright 2024 Jayne Allen"],"dc:subject":["Technoeconomic Analysis","Life Cycle Assessment","Redox-mediated Electrodialysis Downstream Separations","Organic Acid Upconcentration"],"dc:title":["Preliminary framework for quantitative sustainable design of redox-mediated electrodialysis for biorefinery separations"],"dc:type":["Text"],"thesis:degree_discipline":["Environ Engr in Civil Engr"],"thesis:degree_level":["Thesis"],"thesis:degree_name":["M.S."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:25:02Z"}