{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/121234"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/121234","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Characterization and development of composite structured hydrophobic surfaces","abstract":"Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2025-08-01","abstract_html":"Submission published under a 24 month embargo labeled &#x27;Closed Access&#x27;, the embargo will last until 2025-08-01","abstract_has_math":false,"creators":["Chang, Ho Chan"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Mechanical Engineering","degree_department":null,"school":null,"contributors":["Miljkovic, Nenad","Shao, Chenhui","Wang, Sophie","Banerjee, Arijit"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2023,"date_issued":"2023-08","date_published":"2023-08","updated_at":"2026-07-22T22:24:57Z","subjects":["Heat Transfer","Dropwise Condensation","Composite Coating","Hydrophobic Surface","Nanostructure","Microstructure"],"languages":["en","eng"],"rights":["© 2023 HO CHAN CHANG"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/121234","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Miljkovic, Nenad","Shao, Chenhui","Wang, Sophie","Banerjee, Arijit"]},{"key":"dc:creator","label":"Author","values":["Chang, Ho Chan"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2023-08","2023-07-12"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Mechanical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Heat Transfer","Dropwise Condensation","Composite Coating","Hydrophobic Surface","Nanostructure","Microstructure"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["© 2023 HO CHAN CHANG"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/121234"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2025-08-01","The student, Ho Chan Chang, accepted the attached license on 2023-07-09 at 09:55.","The student, Ho Chan Chang, submitted this Dissertation for approval on 2023-07-09 at 10:06.","This Dissertation was approved for publication on 2023-07-12 at 07:31.","DSpace SAF Submission Ingestion Package generated from Vireo submission #19569 on 2023-12-04 at 17:31:48","Dropwise condensation of steam on hydrophobic substrates has a 10X higher heat transfer coefficient compared to filmwise condensation. This can potentially increase 2% overall energy efficiency of steam-based power plants. To promote dropwise condensation, low surface energy hydrophobic coatings (polymers) are typically utilized. The low intrinsic thermal conductivity (k < 1 W/(m·K)) of polymers, however, necessitates that the coating be thin (< 1µm) in order to avoid reducing the overall heat exchanger conductance. However, thin polymeric films easily degrade. The two opposing requirements result in the need for optimization between the durability (thick coating) and the heat transfer (thin coating). In this thesis, to enable high thermal conductivity in thicker coatings, metal-polymer structured surfaces are selected. By using porous structure of metals as inter-connected heat-conducting backbones that are filled with hydrophobic materials, polymer as selected, desired coating effective thermal conductivity and surface energy can be achieved. First, heat transfer performance using metal and polymer composite surface was calculated using three-dimensional finite element method simulations. This result was used to predict the heat transfer performance as a function of metal fraction by volume and by surface area for condensation. By coupling the thermal simulation results with a previously verified analytical model for predicting wetting behavior on heterogeneous surfaces, I propose a regime map to predict dropwise-to-filmwise transition. Based on the results, two actual samples are fabricated: sintered copper powders and copper nanowires, both filled with polydimethylsiloxane (PDMS). The thermal and wettability characterizations are done on both samples. Also, the condensation heat transfer performance is analyzed for copper nanowires. These samples demonstrated a comparable overall heat transfer coefficient to conventional polymer coatings, even with a thicker coating (> 10µm), thereby proposing the possible enhanced durability of the coating. These findings enabled the possibility of durable metal-polymer structured surface usage for industrial applications whereas condensation occurs, enhancing the overall efficiency of thermal systems."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Characterization and development of composite structured hydrophobic surfaces"]}]}],"canonical_facts":{"dc:contributor":["Miljkovic, Nenad","Shao, Chenhui","Wang, Sophie","Banerjee, Arijit"],"dc:creator":["Chang, Ho Chan"],"dc:date":["2023-08","2023-07-12"],"dc:description":["Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2025-08-01","The student, Ho Chan Chang, accepted the attached license on 2023-07-09 at 09:55.","The student, Ho Chan Chang, submitted this Dissertation for approval on 2023-07-09 at 10:06.","This Dissertation was approved for publication on 2023-07-12 at 07:31.","DSpace SAF Submission Ingestion Package generated from Vireo submission #19569 on 2023-12-04 at 17:31:48","Dropwise condensation of steam on hydrophobic substrates has a 10X higher heat transfer coefficient compared to filmwise condensation. This can potentially increase 2% overall energy efficiency of steam-based power plants. To promote dropwise condensation, low surface energy hydrophobic coatings (polymers) are typically utilized. The low intrinsic thermal conductivity (k < 1 W/(m·K)) of polymers, however, necessitates that the coating be thin (< 1µm) in order to avoid reducing the overall heat exchanger conductance. However, thin polymeric films easily degrade. The two opposing requirements result in the need for optimization between the durability (thick coating) and the heat transfer (thin coating). In this thesis, to enable high thermal conductivity in thicker coatings, metal-polymer structured surfaces are selected. By using porous structure of metals as inter-connected heat-conducting backbones that are filled with hydrophobic materials, polymer as selected, desired coating effective thermal conductivity and surface energy can be achieved. First, heat transfer performance using metal and polymer composite surface was calculated using three-dimensional finite element method simulations. This result was used to predict the heat transfer performance as a function of metal fraction by volume and by surface area for condensation. By coupling the thermal simulation results with a previously verified analytical model for predicting wetting behavior on heterogeneous surfaces, I propose a regime map to predict dropwise-to-filmwise transition. Based on the results, two actual samples are fabricated: sintered copper powders and copper nanowires, both filled with polydimethylsiloxane (PDMS). The thermal and wettability characterizations are done on both samples. Also, the condensation heat transfer performance is analyzed for copper nanowires. These samples demonstrated a comparable overall heat transfer coefficient to conventional polymer coatings, even with a thicker coating (> 10µm), thereby proposing the possible enhanced durability of the coating. These findings enabled the possibility of durable metal-polymer structured surface usage for industrial applications whereas condensation occurs, enhancing the overall efficiency of thermal systems."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/121234"],"dc:language":["en","eng"],"dc:rights":["© 2023 HO CHAN CHANG"],"dc:subject":["Heat Transfer","Dropwise Condensation","Composite Coating","Hydrophobic Surface","Nanostructure","Microstructure"],"dc:title":["Characterization and development of composite structured hydrophobic surfaces"],"dc:type":["text"],"thesis:degree_discipline":["Mechanical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:24:57Z"}