{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/117878"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/117878","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Homogeneous flow catalysis strategies for lab-scale kinetic investigation and reaction development","abstract":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2023-05-11 without embargo terms","abstract_html":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2023-05-11 without embargo terms","abstract_has_math":false,"creators":["Wang, Nicholas Mason"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemical Engineering","degree_department":null,"school":null,"contributors":["Guironnet, Damien S.","Peters, Baron G.","Zimmerman, Steven C.","Su, Xiao"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2022,"date_issued":"2022-05","date_published":"2022-05","updated_at":"2026-07-22T22:24:56Z","subjects":["Flow Chemistry","Organometallics","Heterogenization","Reactor Engineering"],"languages":["en","eng"],"rights":["Copyright 2022 Nicholas Wang"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/117878","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Guironnet, Damien S.","Peters, Baron G.","Zimmerman, Steven C.","Su, Xiao"]},{"key":"dc:creator","label":"Author","values":["Wang, Nicholas Mason"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2022-05","2022-04-21"]},{"key":"dc:type","label":"Dc Type","values":["text","Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Flow Chemistry","Organometallics","Heterogenization","Reactor Engineering"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2022 Nicholas Wang"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/117878"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2023-05-11 without embargo terms","The student, Nicholas Wang, accepted the attached license on 2022-04-20 at 09:47.","The student, Nicholas Wang, submitted this Dissertation for approval on 2022-04-20 at 10:01.","This Dissertation was approved for publication on 2022-04-21 at 17:32.","DSpace SAF Submission Ingestion Package generated from Vireo submission #17833 on 2023-05-11 at 16:57:48","Predicated on vapor-liquid separations, we have developed methodologies to effectively immobilize homogeneous organometallic catalysts within a continuous reactor. Compared to the traditional investigation of these catalysts in a batch system, our advanced analysis under steady-state flow provides chemical insight that is not, otherwise, easily accessible. In this dissertation, we detail the design and implementation of these flow methodologies; and overall, the accumulation of our efforts demonstrates the benefit of coupling engineering and chemistry fundamentals toward the development of meaningful catalytic reactions. Chapter 1 contains a brief introduction to catalysis in addition to a mini-review of separation technologies used for the continuous processing of homogeneous catalysts. In Chapter 2, we introduce the catalytic ethanol coupling reaction (the Guerbet reaction), and we provide a detailed mechanistic investigation of a homogeneous ruthenium catalyst within a continuously stirred tank reactor. In a second project described in Chapter 3, we develop supported liquid phase catalysts to effectively immobilize two organometallic complexes for study in a packed bed reactor. We begin Chapter 4 with a summary of current polyolefin depolymerization strategies prior to introducing a new chemical depolymerization technique. By implementing tandem catalytic reactions (dehydrogenation, isomerization, and metathesis) we seek to selectively convert polyethylene to monomer (propylene and butene). Chapter 5 contains an extension of our depolymerization efforts to several promising heterogeneous catalysts."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Homogeneous flow catalysis strategies for lab-scale kinetic investigation and reaction development"]}]}],"canonical_facts":{"dc:contributor":["Guironnet, Damien S.","Peters, Baron G.","Zimmerman, Steven C.","Su, Xiao"],"dc:creator":["Wang, Nicholas Mason"],"dc:date":["2022-05","2022-04-21"],"dc:description":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2023-05-11 without embargo terms","The student, Nicholas Wang, accepted the attached license on 2022-04-20 at 09:47.","The student, Nicholas Wang, submitted this Dissertation for approval on 2022-04-20 at 10:01.","This Dissertation was approved for publication on 2022-04-21 at 17:32.","DSpace SAF Submission Ingestion Package generated from Vireo submission #17833 on 2023-05-11 at 16:57:48","Predicated on vapor-liquid separations, we have developed methodologies to effectively immobilize homogeneous organometallic catalysts within a continuous reactor. Compared to the traditional investigation of these catalysts in a batch system, our advanced analysis under steady-state flow provides chemical insight that is not, otherwise, easily accessible. In this dissertation, we detail the design and implementation of these flow methodologies; and overall, the accumulation of our efforts demonstrates the benefit of coupling engineering and chemistry fundamentals toward the development of meaningful catalytic reactions. Chapter 1 contains a brief introduction to catalysis in addition to a mini-review of separation technologies used for the continuous processing of homogeneous catalysts. In Chapter 2, we introduce the catalytic ethanol coupling reaction (the Guerbet reaction), and we provide a detailed mechanistic investigation of a homogeneous ruthenium catalyst within a continuously stirred tank reactor. In a second project described in Chapter 3, we develop supported liquid phase catalysts to effectively immobilize two organometallic complexes for study in a packed bed reactor. We begin Chapter 4 with a summary of current polyolefin depolymerization strategies prior to introducing a new chemical depolymerization technique. By implementing tandem catalytic reactions (dehydrogenation, isomerization, and metathesis) we seek to selectively convert polyethylene to monomer (propylene and butene). Chapter 5 contains an extension of our depolymerization efforts to several promising heterogeneous catalysts."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/117878"],"dc:language":["en","eng"],"dc:rights":["Copyright 2022 Nicholas Wang"],"dc:subject":["Flow Chemistry","Organometallics","Heterogenization","Reactor Engineering"],"dc:title":["Homogeneous flow catalysis strategies for lab-scale kinetic investigation and reaction development"],"dc:type":["text","Thesis"],"thesis:degree_discipline":["Chemical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:24:56Z"}