{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/116204"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/116204","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Multiscale models for polymer upcycling","abstract":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2022-11-15 without embargo terms","abstract_html":"Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2022-11-15 without embargo terms","abstract_has_math":false,"creators":["Yappert, Ryan Davis"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemical Engineering","degree_department":null,"school":null,"contributors":["Peters, Baron G","Moore, Jeffrey S","Sing, Charles E","Statt, Antonia"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2022,"date_issued":"2022-08","date_published":"2022-08","updated_at":"2026-07-22T22:24:55Z","subjects":["polymer upcycling","processive catalysis","population balance models","mathematical modeling","lumped models"],"languages":["en","eng"],"rights":["Copyright 2022 Ryan Yappert"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2142/116204","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Peters, Baron G","Moore, Jeffrey S","Sing, Charles E","Statt, Antonia"]},{"key":"dc:creator","label":"Author","values":["Yappert, Ryan Davis"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2022-08","2022-07-11"]},{"key":"dc:type","label":"Dc Type","values":["text","Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemical Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["polymer upcycling","processive catalysis","population balance models","mathematical modeling","lumped models"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en","eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2022 Ryan Yappert"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/2142/116204"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2022-11-15 without embargo terms","The student, Ryan Yappert, accepted the attached license on 2022-07-10 at 23:18.","The student, Ryan Yappert, submitted this Dissertation for approval on 2022-07-10 at 23:25.","This Dissertation was approved for publication on 2022-07-11 at 15:51.","DSpace SAF Submission Ingestion Package generated from Vireo submission #18206 on 2022-11-15 at 17:38:40","Millions of tons of plastic waste are discarded every year, most of it ending up in landfills or the ocean. While some is recycled, the most common plastic recycling techniques used today either involve simple burning of plastic waste, or mechanically breaking down waste into small pellets that may be repurposed in less valuable products with lower engineering demands. Chemical and catalytic upcycling processes could help to realize a circular plastics economy, by breaking down plastic waste into products that may be reused in products of equal or greater value, such as lubricants, oils, and chemical feedstocks. However, existing models for testing mechanistic hypotheses and designing catalysts remain primitive. Coarse-graining and other molecular simulation techniques can capture the interactions between polymer chains and a catalyst surface but cannot explore the time and length scales of depolymerization experiments. Numerical techniques such as population balance models are easily extended to these scales, but in turn often avoid introducing polymer-surface interactions that complicate their development and solution. In this thesis, we develop new methods for modeling the depolymerization of linear polymers. These models incorporate catalytic mechanisms to predict the time evolution of molecular weight distributions. We consider models for homogeneous and heterogeneous catalysts, including catalysts that cut at random locations, catalysts that cut at chain ends, and catalysts that incorporate processive motifs. We develop solutions to the models, illustrate the effect of adsorption parameters on the evolving molecular weight distribution, identify signatures of heterogeneous mechanisms, and provide a framework for analysis of experimental data to obtain underlying catalytic rate parameters. Where population balance methods are unsuitable, we develop models at alternative scales that better align with experimental observables. These models incorporate unique catalytic mechanisms such as tandem aromatization and competitive adsorption to predict reaction products and extract kinetic parameters."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Multiscale models for polymer upcycling"]}]}],"canonical_facts":{"dc:contributor":["Peters, Baron G","Moore, Jeffrey S","Sing, Charles E","Statt, Antonia"],"dc:creator":["Yappert, Ryan Davis"],"dc:date":["2022-08","2022-07-11"],"dc:description":["Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2022-11-15 without embargo terms","The student, Ryan Yappert, accepted the attached license on 2022-07-10 at 23:18.","The student, Ryan Yappert, submitted this Dissertation for approval on 2022-07-10 at 23:25.","This Dissertation was approved for publication on 2022-07-11 at 15:51.","DSpace SAF Submission Ingestion Package generated from Vireo submission #18206 on 2022-11-15 at 17:38:40","Millions of tons of plastic waste are discarded every year, most of it ending up in landfills or the ocean. While some is recycled, the most common plastic recycling techniques used today either involve simple burning of plastic waste, or mechanically breaking down waste into small pellets that may be repurposed in less valuable products with lower engineering demands. Chemical and catalytic upcycling processes could help to realize a circular plastics economy, by breaking down plastic waste into products that may be reused in products of equal or greater value, such as lubricants, oils, and chemical feedstocks. However, existing models for testing mechanistic hypotheses and designing catalysts remain primitive. Coarse-graining and other molecular simulation techniques can capture the interactions between polymer chains and a catalyst surface but cannot explore the time and length scales of depolymerization experiments. Numerical techniques such as population balance models are easily extended to these scales, but in turn often avoid introducing polymer-surface interactions that complicate their development and solution. In this thesis, we develop new methods for modeling the depolymerization of linear polymers. These models incorporate catalytic mechanisms to predict the time evolution of molecular weight distributions. We consider models for homogeneous and heterogeneous catalysts, including catalysts that cut at random locations, catalysts that cut at chain ends, and catalysts that incorporate processive motifs. We develop solutions to the models, illustrate the effect of adsorption parameters on the evolving molecular weight distribution, identify signatures of heterogeneous mechanisms, and provide a framework for analysis of experimental data to obtain underlying catalytic rate parameters. Where population balance methods are unsuitable, we develop models at alternative scales that better align with experimental observables. These models incorporate unique catalytic mechanisms such as tandem aromatization and competitive adsorption to predict reaction products and extract kinetic parameters."],"dc:format":["application/pdf"],"dc:identifier":["https://hdl.handle.net/2142/116204"],"dc:language":["en","eng"],"dc:rights":["Copyright 2022 Ryan Yappert"],"dc:subject":["polymer upcycling","processive catalysis","population balance models","mathematical modeling","lumped models"],"dc:title":["Multiscale models for polymer upcycling"],"dc:type":["text","Thesis"],"thesis:degree_discipline":["Chemical Engineering"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:24:55Z"}