{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/102782"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/102782","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Organic materials for the improvement and understanding of electrochemical devices","abstract":"Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2020-12-01","abstract_html":"Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2020-12-01","abstract_has_math":false,"creators":["Petronico, Aaron"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Nuzzo, Ralph G.","Gewirth, Andrew A.","Braun, Paul V.","Rodríguez-López, Joaquín"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2019,"date_issued":"2019-02-07T20:35:53Z","date_published":"2019-02-07T20:35:53Z","updated_at":"2026-07-22T22:24:42Z","subjects":["Battery, Cathode, Organic, Electrochemistry"],"languages":["en"],"rights":["Copyright 2018 Aaron Petronico"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/2142/102782","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Nuzzo, Ralph G.","Gewirth, Andrew A.","Braun, Paul V.","Rodríguez-López, Joaquín"]},{"key":"dc:creator","label":"Author","values":["Petronico, Aaron"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2019-02-07T20:35:53Z","2021-02-08T10:15:29Z","2018-10-05","2018-12"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Battery, Cathode, Organic, Electrochemistry"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright 2018 Aaron Petronico"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/102782"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2020-12-01","The student, Aaron Petronico, accepted the attached license on 2018-10-02 at 07:25.","The student, Aaron Petronico, submitted this Dissertation for approval on 2018-10-02 at 07:30.","This Dissertation was approved for publication on 2018-10-05 at 11:52.","DSpace SAF Submission Ingestion Package generated from Vireo submission #13026 on 2019-02-07 at 14:16:41","The contents of this thesis focus on how organic materials can be applied to improve Li+ based batteries. There is specific focus mostly on cathode materials and a single project involving electrolytes. For cathodes the main focus is how quinone polymers can be applied as Li+ cathodes and results in a 4e- cathode with record breaking capacity. We then go on to do some minor mechanistic and fundamental studies. The second cathode focus is how organic materials can augment existing technology. In this regard we investigate how alkyl phosphonates can form monolayer coating on Lithium Manganese Oxide cathode particles to suppress Mn dissolution during cycling. Finally we modify Li-S cathodes by chemically crosslinking poly-sulfide with conductive poly aniline to increase cycle life and cathode sulfur loadings. To improve Li+ electrolytes we demonstrate that persistently porous organic cages can serve as host structures to form solid-liquid electrolyte nano-composites. Taken together this work demonstrates the innovative impact Organic materials can have on battery technology.","Made available in DSpace on 2019-02-07T20:35:53Z (GMT). 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There is specific focus mostly on cathode materials and a single project involving electrolytes. For cathodes the main focus is how quinone polymers can be applied as Li+ cathodes and results in a 4e- cathode with record breaking capacity. We then go on to do some minor mechanistic and fundamental studies. The second cathode focus is how organic materials can augment existing technology. In this regard we investigate how alkyl phosphonates can form monolayer coating on Lithium Manganese Oxide cathode particles to suppress Mn dissolution during cycling. Finally we modify Li-S cathodes by chemically crosslinking poly-sulfide with conductive poly aniline to increase cycle life and cathode sulfur loadings. To improve Li+ electrolytes we demonstrate that persistently porous organic cages can serve as host structures to form solid-liquid electrolyte nano-composites. Taken together this work demonstrates the innovative impact Organic materials can have on battery technology.","Made available in DSpace on 2019-02-07T20:35:53Z (GMT). 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