{"id":{"repo_id":"ucf","oai_identifier":"oai:stars.library.ucf.edu:etd-1015"},"canonical_url":"https://search.dev.ndltd.org/etd/ucf/oai:stars.library.ucf.edu:etd-1015","repository":{"repo_id":"ucf","name":"Central Florida","base_url":"https://stars.library.ucf.edu/do/oai/"},"display":{"title":"Water Quality Variations During Nitrification In Drinking Water Distribution Systems","abstract":"This thesis documents the relationship among the major water quality parameters during a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilot drinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1 Cl2:NH3-N. Surface, ground and sea water were treated and disinfected with monochloramines to produce finished water quality similar to regional utility water quality. PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regional distribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSs were operated at a 5-day hydraulic residence time (HRT) and ambient temperatures. As seasonal temperatures increased the rate of monochloramine dissipation increased until effluent PDS residuals were zero. PDSs effluent water quality parameters chloramines residual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogen species were monitored and found to vary as expected by stoichiometry associated with theoretical biological reactions excepting alkalinity. Nitrification was confirmed in the PDSs. The occurrence in the PDSs was not isolated to any particular source water. Ammonia for nitrification came from degraded chloramines, which was common among all finished waters. Consistent with nitrification trends of dissolved oxygen consumption, ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulk water quality profiles. Trends of pH and alkalinity were less apparent. To control nitrification: residual was increased to 4.5 mg/L as Cl2 at 5:1 Cl2:NH3-N dosing ratio, and the HRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achieved after a 1 week free chlorine burn.","abstract_html":"This thesis documents the relationship among the major water quality parameters during a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilot drinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1 Cl2:NH3-N. Surface, ground and sea water were treated and disinfected with monochloramines to produce finished water quality similar to regional utility water quality. PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regional distribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSs were operated at a 5-day hydraulic residence time (HRT) and ambient temperatures. As seasonal temperatures increased the rate of monochloramine dissipation increased until effluent PDS residuals were zero. PDSs effluent water quality parameters chloramines residual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogen species were monitored and found to vary as expected by stoichiometry associated with theoretical biological reactions excepting alkalinity. Nitrification was confirmed in the PDSs. The occurrence in the PDSs was not isolated to any particular source water. Ammonia for nitrification came from degraded chloramines, which was common among all finished waters. Consistent with nitrification trends of dissolved oxygen consumption, ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulk water quality profiles. Trends of pH and alkalinity were less apparent. To control nitrification: residual was increased to 4.5 mg/L as Cl2 at 5:1 Cl2:NH3-N dosing ratio, and the HRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achieved after a 1 week free chlorine burn.","abstract_has_math":false,"creators":["Webb, David W"],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["Taylor, James S."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2004,"date_issued":"2004-01-01T08:00:00Z","date_published":"2004-01-01T08:00:00Z","updated_at":"2026-07-24T05:08:08Z","subjects":["Chloramines","Distribution system","Drinking water","Nitrification","Civil and Environmental Engineering","Engineering","Dissertations, Academic -- Engineering and Computer Science; Engineering and Computer Science -- Dissertations, Academic"],"languages":["English"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["CFE0000063"],"render_values":[{"text":"CFE0000063","href":null,"code":true}]}]},"links":{"outbound_url":"https://stars.library.ucf.edu/etd/16","outbound_label":"Repository record","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Taylor, James S."]},{"key":"dc:creator","label":"Author","values":["Webb, David W"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:type","label":"Dc Type","values":["Masters Thesis (Open Access)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chloramines","Distribution system","Drinking water","Nitrification","Civil and Environmental Engineering","Engineering","Dissertations, Academic -- Engineering and Computer Science; Engineering and Computer Science -- Dissertations, Academic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["CFE0000063"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://stars.library.ucf.edu/etd/16"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["<p>If this is your thesis or dissertation, and want to learn how to access it or for more information about readership statistics, contact us at <a href=\"mailto:STARS@ucf.edu\">STARS@ucf.edu</a></p>","Master of Science (M.S.)","College of Engineering and Computer Science","Civil and Environmental Engineering"]},{"key":"dc:description.abstract","label":"Abstract","values":["This thesis documents the relationship among the major water quality parameters during a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilot drinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1 Cl2:NH3-N. Surface, ground and sea water were treated and disinfected with monochloramines to produce finished water quality similar to regional utility water quality. PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regional distribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSs were operated at a 5-day hydraulic residence time (HRT) and ambient temperatures. As seasonal temperatures increased the rate of monochloramine dissipation increased until effluent PDS residuals were zero. PDSs effluent water quality parameters chloramines residual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogen species were monitored and found to vary as expected by stoichiometry associated with theoretical biological reactions excepting alkalinity. Nitrification was confirmed in the PDSs. The occurrence in the PDSs was not isolated to any particular source water. Ammonia for nitrification came from degraded chloramines, which was common among all finished waters. Consistent with nitrification trends of dissolved oxygen consumption, ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulk water quality profiles. Trends of pH and alkalinity were less apparent. To control nitrification: residual was increased to 4.5 mg/L as Cl2 at 5:1 Cl2:NH3-N dosing ratio, and the HRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achieved after a 1 week free chlorine burn."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Water Quality Variations During Nitrification In Drinking Water Distribution Systems"]}]}],"canonical_facts":{"dc:contributor":["Taylor, James S."],"dc:creator":["Webb, David W"],"dc:description":["<p>If this is your thesis or dissertation, and want to learn how to access it or for more information about readership statistics, contact us at <a href=\"mailto:STARS@ucf.edu\">STARS@ucf.edu</a></p>","Master of Science (M.S.)","College of Engineering and Computer Science","Civil and Environmental Engineering"],"dc:description.abstract":["This thesis documents the relationship among the major water quality parameters during a nitrification episode. Nitrification unexpectedly occurred in a chloraminated pilot drinking water distribution system practicing with a 4.0 mg/L as Cl2 residual dosed at 4.5:1 Cl2:NH3-N. Surface, ground and sea water were treated and disinfected with monochloramines to produce finished water quality similar to regional utility water quality. PVC, galvanized, unlined cast iron and lined iron pipes were harvested from regional distribution systems and used to build eighteen pilot distribution systems (PDSs). The PDSs were operated at a 5-day hydraulic residence time (HRT) and ambient temperatures. As seasonal temperatures increased the rate of monochloramine dissipation increased until effluent PDS residuals were zero. PDSs effluent water quality parameters chloramines residual, dissolved oxygen, heterotrophic plate counts (HPCs), pH, alkalinity, and nitrogen species were monitored and found to vary as expected by stoichiometry associated with theoretical biological reactions excepting alkalinity. Nitrification was confirmed in the PDSs. The occurrence in the PDSs was not isolated to any particular source water. Ammonia for nitrification came from degraded chloramines, which was common among all finished waters. Consistent with nitrification trends of dissolved oxygen consumption, ammonia consumption, nitrite and nitrate production were clearly observed in the PDSs bulk water quality profiles. Trends of pH and alkalinity were less apparent. To control nitrification: residual was increased to 4.5 mg/L as Cl2 at 5:1 Cl2:NH3-N dosing ratio, and the HRT was reduced from 5 to 2 days. Elimination of the nitrification episode was achieved after a 1 week free chlorine burn."],"dc:format":["application/pdf"],"dc:identifier":["CFE0000063"],"dc:identifier.uri":["https://stars.library.ucf.edu/etd/16"],"dc:language":["English"],"dc:subject":["Chloramines","Distribution system","Drinking water","Nitrification","Civil and Environmental Engineering","Engineering","Dissertations, Academic -- Engineering and Computer Science; Engineering and Computer Science -- Dissertations, Academic"],"dc:title":["Water Quality Variations During Nitrification In Drinking Water Distribution Systems"],"dc:type":["Masters Thesis (Open Access)"]},"updated_at":"2026-07-24T05:08:08Z"}