{"id":{"repo_id":"u-pacific","oai_identifier":"oai:scholarlycommons.pacific.edu:uop_etds-2900"},"canonical_url":"https://search.dev.ndltd.org/etd/u-pacific/oai:scholarlycommons.pacific.edu:uop_etds-2900","repository":{"repo_id":"u-pacific","name":"University of the Pacific","base_url":"https://scholarlycommons.pacific.edu/do/oai/"},"display":{"title":"Kinetics and stoichiometry of the aquation reaction of pentaaquomonobromomethylchromium (III) perchlorate","abstract":"The purpose of this thesis was to determine the kinetics and stoichiometry for the aquation of the pentaaquomonobromonmethylchromium(III) complex. The complex was prepared by the reduction of dibromomethane by chromium(II). The products of aquation, in the absence of oxygen, were found to be hexaaquachromium(III), methanol, and bromide. The balanced net ionic reaction can be written: 2H<sub>2</sub>O + (H<sub>2</sub>O)<sub>5</sub>CrCH<sub>2</sub>Br<sup>2+</sup> → (H<sub>2</sub>O)<sub>6</sub>Cr<sup>3+</sup> + CH<sub>3</sub>OH + Br<sup>-</sup>","abstract_html":"The purpose of this thesis was to determine the kinetics and stoichiometry for the aquation of the pentaaquomonobromonmethylchromium(III) complex. The complex was prepared by the reduction of dibromomethane by chromium(II). The products of aquation, in the absence of oxygen, were found to be hexaaquachromium(III), methanol, and bromide. The balanced net ionic reaction can be written: 2H&lt;sub&gt;2&lt;/sub&gt;O + (H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;5&lt;/sub&gt;CrCH&lt;sub&gt;2&lt;/sub&gt;Br&lt;sup&gt;2+&lt;/sup&gt; → (H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;6&lt;/sub&gt;Cr&lt;sup&gt;3+&lt;/sup&gt; + CH&lt;sub&gt;3&lt;/sub&gt;OH + Br&lt;sup&gt;-&lt;/sup&gt;","abstract_has_math":false,"creators":["Byington, Janice Imada"],"institution":null,"degree_name":"Master of Science (M.S.)","degree_level":"Thesis","degree_discipline":"Graduate School","degree_department":null,"school":null,"contributors":["Larry O. Spreer"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1976,"date_issued":"1976-01-01T08:00:00Z","date_published":"1976-01-01T08:00:00Z","updated_at":"2026-07-24T05:37:42Z","subjects":["Organochromium compounds Reactivity","Chemical kinetics","Stoichiometry","Physical Sciences and Mathematics"],"languages":[],"rights":[],"rights_urls":["http://rightsstatements.org/vocab/NKC/1.0/"],"identifier_entries":[]},"links":{"outbound_url":"https://scholarlycommons.pacific.edu/uop_etds/1901","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Larry O. 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The complex was prepared by the reduction of dibromomethane by chromium(II). The products of aquation, in the absence of oxygen, were found to be hexaaquachromium(III), methanol, and bromide. The balanced net ionic reaction can be written: 2H<sub>2</sub>O + (H<sub>2</sub>O)<sub>5</sub>CrCH<sub>2</sub>Br<sup>2+</sup> → (H<sub>2</sub>O)<sub>6</sub>Cr<sup>3+</sup> + CH<sub>3</sub>OH + Br<sup>-</sup>"]},{"key":"dc:source","label":"Dc Source","values":["79"]},{"key":"dc:title","label":"Title","values":["Kinetics and stoichiometry of the aquation reaction of pentaaquomonobromomethylchromium (III) perchlorate"]}]}],"canonical_facts":{"dc:contributor":["Larry O. Spreer"],"dc:creator":["Byington, Janice Imada"],"dc:date.available":["2018-06-29T09:02:08Z"],"dc:description.abstract":["The purpose of this thesis was to determine the kinetics and stoichiometry for the aquation of the pentaaquomonobromonmethylchromium(III) complex. The complex was prepared by the reduction of dibromomethane by chromium(II). The products of aquation, in the absence of oxygen, were found to be hexaaquachromium(III), methanol, and bromide. The balanced net ionic reaction can be written: 2H<sub>2</sub>O + (H<sub>2</sub>O)<sub>5</sub>CrCH<sub>2</sub>Br<sup>2+</sup> → (H<sub>2</sub>O)<sub>6</sub>Cr<sup>3+</sup> + CH<sub>3</sub>OH + Br<sup>-</sup>"],"dc:identifier":["https://scholarlycommons.pacific.edu/uop_etds/1901"],"dc:rights":["http://rightsstatements.org/vocab/NKC/1.0/"],"dc:source":["79"],"dc:subject":["Organochromium compounds Reactivity","Chemical kinetics","Stoichiometry","Physical Sciences and Mathematics"],"dc:title":["Kinetics and stoichiometry of the aquation reaction of pentaaquomonobromomethylchromium (III) perchlorate"],"thesis:degree_discipline":["Graduate School"],"thesis:degree_level":["Thesis"],"thesis:degree_name":["Master of Science (M.S.)"]},"updated_at":"2026-07-24T05:37:42Z"}