Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH3)4]Cl2 Tetraammine Palladium (II) Chloride. [Pd (NH3)4]Cl2 Hexammine Platinum (IV) Chloride. [Pt (NH3)6]Cl4 Hexammine Palladium (IV) Chloride [Pd (NH3)6]Cl4
After the complexes had been synthesized, the main problem lay in finding a suitable adsorbent and solvent system for separating a mixture of all four complexes as well as an appropriate locating reagent, so that once the separation had been accomplished, complexes could be identified.
","abstract_html":"<p>Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH<sub>3</sub>)<sub>4</sub>]Cl<sub>2</sub> Tetraammine Palladium (II) Chloride. [Pd (NH<sub>3</sub>)<sub>4</sub>]Cl<sub>2</sub> Hexammine Platinum (IV) Chloride. [Pt (NH<sub>3</sub>)<sub>6</sub>]Cl<sub>4</sub> Hexammine Palladium (IV) Chloride [Pd (NH<sub>3</sub>)<sub>6</sub>]Cl<sub>4</sub></p><p>After the complexes had been synthesized, the main problem lay in finding a suitable adsorbent and solvent system for separating a mixture of all four complexes as well as an appropriate locating reagent, so that once the separation had been accomplished, complexes could be identified.</p>","abstract_has_math":false,"creators":["Montezuma, Edgar Roberto"],"institution":null,"degree_name":"Master of Science (M.S.)","degree_level":"Thesis","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Herschel Frye"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1968,"date_issued":"1968-01-01T08:00:00Z","date_published":"1968-01-01T08:00:00Z","updated_at":"2026-07-24T05:37:34Z","subjects":["Thin layer chromatography","Organoplatinum compounds","Amines","Chemistry","Physical Sciences and Mathematics"],"languages":[],"rights":[],"rights_urls":["http://rightsstatements.org/vocab/NKC/1.0/"],"identifier_entries":[]},"links":{"outbound_url":"https://scholarlycommons.pacific.edu/uop_etds/1665","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Herschel Frye"]},{"key":"dc:creator","label":"Author","values":["Montezuma, Edgar Roberto"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2018-06-29T08:42:28Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (M.S.)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Thin layer chromatography","Organoplatinum compounds","Amines","Chemistry","Physical Sciences and Mathematics"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["http://rightsstatements.org/vocab/NKC/1.0/"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://scholarlycommons.pacific.edu/uop_etds/1665"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH3)4]Cl2 Tetraammine Palladium (II) Chloride. [Pd (NH3)4]Cl2 Hexammine Platinum (IV) Chloride. [Pt (NH3)6]Cl4 Hexammine Palladium (IV) Chloride [Pd (NH3)6]Cl4
After the complexes had been synthesized, the main problem lay in finding a suitable adsorbent and solvent system for separating a mixture of all four complexes as well as an appropriate locating reagent, so that once the separation had been accomplished, complexes could be identified.
"]},{"key":"dc:source","label":"Dc Source","values":["56"]},{"key":"dc:title","label":"Title","values":["Thin layer chromatography of platinum and palladium-ammine complexes"]}]}],"canonical_facts":{"dc:contributor":["Herschel Frye"],"dc:creator":["Montezuma, Edgar Roberto"],"dc:date.available":["2018-06-29T08:42:28Z"],"dc:description.abstract":["Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH3)4]Cl2 Tetraammine Palladium (II) Chloride. [Pd (NH3)4]Cl2 Hexammine Platinum (IV) Chloride. [Pt (NH3)6]Cl4 Hexammine Palladium (IV) Chloride [Pd (NH3)6]Cl4
After the complexes had been synthesized, the main problem lay in finding a suitable adsorbent and solvent system for separating a mixture of all four complexes as well as an appropriate locating reagent, so that once the separation had been accomplished, complexes could be identified.
"],"dc:identifier":["https://scholarlycommons.pacific.edu/uop_etds/1665"],"dc:rights":["http://rightsstatements.org/vocab/NKC/1.0/"],"dc:source":["56"],"dc:subject":["Thin layer chromatography","Organoplatinum compounds","Amines","Chemistry","Physical Sciences and Mathematics"],"dc:title":["Thin layer chromatography of platinum and palladium-ammine complexes"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Thesis"],"thesis:degree_name":["Master of Science (M.S.)"]},"updated_at":"2026-07-24T05:37:34Z"}