COF-18Å is one type of Covalent Organic Framework (COF) that incorporates self-assembling covalent bonded boronate esters as secondary building units to form a porous material. COF-18Å has the ability to store gases, high surface areas, good thermal stability, but is susceptible to hydrolysis. Preliminary results show that the covalent organic frameworks have the ability to be repaired, recycled, and resynthesized after hydrolysis. Further exploration of porous materials incorporating boronate esters explores the use of empty p-orbital of the boronate ester. The formation of boron nitrogen dative bond results in the engineering of Supramolecular Boronate Materials a new class of porous materials.
","abstract_html":"<p> COF-18Å is one type of Covalent Organic Framework (COF) that incorporates self-assembling covalent bonded boronate esters as secondary building units to form a porous material. COF-18Å has the ability to store gases, high surface areas, good thermal stability, but is susceptible to hydrolysis. Preliminary results show that the covalent organic frameworks have the ability to be repaired, recycled, and resynthesized after hydrolysis. Further exploration of porous materials incorporating boronate esters explores the use of empty p-orbital of the boronate ester. The formation of boron nitrogen dative bond results in the engineering of Supramolecular Boronate Materials a new class of porous materials.</p>","abstract_has_math":false,"creators":["Sapp, Kevin Scott"],"institution":null,"degree_name":"M.S.","degree_level":"Campus Access Thesis","degree_discipline":"Chemistry and Biochemistry","degree_department":null,"school":null,"contributors":["John J Lavigne","Ken D Shimizu"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2011,"date_issued":"2011-01-01T08:00:00Z","date_published":"2011-01-01T08:00:00Z","updated_at":"2026-07-24T04:37:49Z","subjects":["Chemistry","Physical Sciences and Mathematics","Boronate Esters","Boronic Acid","Boron Nitrogen Dative Bond","Covalent Organic Frameworks","Self-assembly","Supramolecular Boronate Materials"],"languages":[],"rights":["© 2011, Kevin Scott Sapp"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://scholarcommons.sc.edu/etd/730","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["John J Lavigne","Ken D Shimizu"]},{"key":"dc:creator","label":"Author","values":["Sapp, Kevin Scott"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry and Biochemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Campus Access Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.S."]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry","Physical Sciences and Mathematics","Boronate Esters","Boronic Acid","Boron Nitrogen Dative Bond","Covalent Organic Frameworks","Self-assembly","Supramolecular Boronate Materials"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["© 2011, Kevin Scott Sapp"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://scholarcommons.sc.edu/etd/730"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["COF-18Å is one type of Covalent Organic Framework (COF) that incorporates self-assembling covalent bonded boronate esters as secondary building units to form a porous material. COF-18Å has the ability to store gases, high surface areas, good thermal stability, but is susceptible to hydrolysis. Preliminary results show that the covalent organic frameworks have the ability to be repaired, recycled, and resynthesized after hydrolysis. Further exploration of porous materials incorporating boronate esters explores the use of empty p-orbital of the boronate ester. The formation of boron nitrogen dative bond results in the engineering of Supramolecular Boronate Materials a new class of porous materials.
"]},{"key":"dc:title","label":"Title","values":["Study of Porous Materials Incorporating Boronate Esters"]}]}],"canonical_facts":{"dc:contributor":["John J Lavigne","Ken D Shimizu"],"dc:creator":["Sapp, Kevin Scott"],"dc:description.abstract":["COF-18Å is one type of Covalent Organic Framework (COF) that incorporates self-assembling covalent bonded boronate esters as secondary building units to form a porous material. COF-18Å has the ability to store gases, high surface areas, good thermal stability, but is susceptible to hydrolysis. Preliminary results show that the covalent organic frameworks have the ability to be repaired, recycled, and resynthesized after hydrolysis. Further exploration of porous materials incorporating boronate esters explores the use of empty p-orbital of the boronate ester. The formation of boron nitrogen dative bond results in the engineering of Supramolecular Boronate Materials a new class of porous materials.
"],"dc:identifier":["https://scholarcommons.sc.edu/etd/730"],"dc:rights":["© 2011, Kevin Scott Sapp"],"dc:subject":["Chemistry","Physical Sciences and Mathematics","Boronate Esters","Boronic Acid","Boron Nitrogen Dative Bond","Covalent Organic Frameworks","Self-assembly","Supramolecular Boronate Materials"],"dc:title":["Study of Porous Materials Incorporating Boronate Esters"],"thesis:degree_discipline":["Chemistry and Biochemistry"],"thesis:degree_level":["Campus Access Thesis"],"thesis:degree_name":["M.S."]},"updated_at":"2026-07-24T04:37:49Z"}