{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/89716"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/89716","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"Laser produced vaporization of materials for use in mass spectroscopic analysis","abstract":"The focused output of certain solid state lasers can be used to produce rapid surface heating and consequent vaporization in absorbing materials. For ordinary lasers it appears that the heating process can be adequately explained on the basis of a relatively simple classical thermodynamic treatment; however, for Q-switched lasers it is much more complicated. John F. Ready has presented a theoretical treatment for both cases, and the experimental results with metals agree well with theory. The use of time of flight mass spectrometer to study vaporized material results in a useful analytical tool for study of sample composition and provides information about laser beam-surface interaction as well. Employing a mass spectrometer, a complete spectrum of almost any material, including complex organic substances, can be obtained from a selected surface area, and small chemical concentrations can be detected. In what follows the vaporization process appropriate to ordinary lasers of moderate power output is discussed, and experimental results in the form of mass spectrograms of several substances obtained with a Bendix time-of-flight instrument are presented. Also, the equipment employed is described in detail with particular emphasis on the laser system and experimental difficulties which were encountered.","abstract_html":"The focused output of certain solid state lasers can be used to produce rapid surface heating and consequent vaporization in absorbing materials. For ordinary lasers it appears that the heating process can be adequately explained on the basis of a relatively simple classical thermodynamic treatment; however, for Q-switched lasers it is much more complicated. John F. Ready has presented a theoretical treatment for both cases, and the experimental results with metals agree well with theory. The use of time of flight mass spectrometer to study vaporized material results in a useful analytical tool for study of sample composition and provides information about laser beam-surface interaction as well. Employing a mass spectrometer, a complete spectrum of almost any material, including complex organic substances, can be obtained from a selected surface area, and small chemical concentrations can be detected. In what follows the vaporization process appropriate to ordinary lasers of moderate power output is discussed, and experimental results in the form of mass spectrograms of several substances obtained with a Bendix time-of-flight instrument are presented. Also, the equipment employed is described in detail with particular emphasis on the laser system and experimental difficulties which were encountered.","abstract_has_math":false,"creators":["Turner, Terry Arthur"],"institution":"Rice University","degree_name":"Master of Science","degree_level":"Masters","degree_discipline":"Engineering","degree_department":null,"school":null,"contributors":[],"advisors":["Rabson, Thomas A."],"committee_chairs":[],"committee_members":[],"year":1968,"date_issued":"1968","date_published":"1968","updated_at":"2026-07-24T04:10:26Z","subjects":[],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/89716","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Rabson, Thomas A."]},{"key":"dc:creator","label":"Author","values":["Turner, Terry Arthur"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-04-22T21:58:15Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-04-22T21:58:15Z"]},{"key":"dc:date.issued","label":"Date","values":["1968"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/1911/89716"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The focused output of certain solid state lasers can be used to produce rapid surface heating and consequent vaporization in absorbing materials. For ordinary lasers it appears that the heating process can be adequately explained on the basis of a relatively simple classical thermodynamic treatment; however, for Q-switched lasers it is much more complicated. John F. Ready has presented a theoretical treatment for both cases, and the experimental results with metals agree well with theory. The use of time of flight mass spectrometer to study vaporized material results in a useful analytical tool for study of sample composition and provides information about laser beam-surface interaction as well. Employing a mass spectrometer, a complete spectrum of almost any material, including complex organic substances, can be obtained from a selected surface area, and small chemical concentrations can be detected. In what follows the vaporization process appropriate to ordinary lasers of moderate power output is discussed, and experimental results in the form of mass spectrograms of several substances obtained with a Bendix time-of-flight instrument are presented. Also, the equipment employed is described in detail with particular emphasis on the laser system and experimental difficulties which were encountered."]},{"key":"dc:title","label":"Title","values":["Laser produced vaporization of materials for use in mass spectroscopic analysis"]}]}],"canonical_facts":{"dc:contributor.advisor":["Rabson, Thomas A."],"dc:creator":["Turner, Terry Arthur"],"dc:date.accessioned":["2016-04-22T21:58:15Z"],"dc:date.available":["2016-04-22T21:58:15Z"],"dc:date.issued":["1968"],"dc:description.abstract":["The focused output of certain solid state lasers can be used to produce rapid surface heating and consequent vaporization in absorbing materials. For ordinary lasers it appears that the heating process can be adequately explained on the basis of a relatively simple classical thermodynamic treatment; however, for Q-switched lasers it is much more complicated. John F. Ready has presented a theoretical treatment for both cases, and the experimental results with metals agree well with theory. The use of time of flight mass spectrometer to study vaporized material results in a useful analytical tool for study of sample composition and provides information about laser beam-surface interaction as well. Employing a mass spectrometer, a complete spectrum of almost any material, including complex organic substances, can be obtained from a selected surface area, and small chemical concentrations can be detected. In what follows the vaporization process appropriate to ordinary lasers of moderate power output is discussed, and experimental results in the form of mass spectrograms of several substances obtained with a Bendix time-of-flight instrument are presented. Also, the equipment employed is described in detail with particular emphasis on the laser system and experimental difficulties which were encountered."],"dc:identifier.uri":["https://hdl.handle.net/1911/89716"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:title":["Laser produced vaporization of materials for use in mass spectroscopic analysis"],"dc:type":["Thesis"],"thesis:degree_discipline":["Engineering"],"thesis:degree_level":["Masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:26Z"}