{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/89362"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/89362","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"The oxidation of carbon monoxide on zinc oxide","abstract":"A study was made of the kinetics of the oxidation of carbon monoxide to form carbon dioxide. The catalyst was high purity zinc oxide. A liquid nitrogen trap was used to remove the product carbon dioxide, thereby virtually eliminating any poisoning effect of CO2 on the reaction. A natural convection loop provided the means for circulating gases past the catalyst and the nitrogen trap in the batch system. Pressure change due to reaction was the criterion used to determine the kinetics. The reactions were studied between 250°C and 310°C, with initial total pressure of approximately 35 torr. The overall order dependency was found to be approximately 1.1, with individual orders of approximately 0.9 and 0.2 for carbon monoxide and oxygen, respectively. The apparent activation energy for the reaction was found to be 15.1 Kcal/mole.","abstract_html":"A study was made of the kinetics of the oxidation of carbon monoxide to form carbon dioxide. The catalyst was high purity zinc oxide. A liquid nitrogen trap was used to remove the product carbon dioxide, thereby virtually eliminating any poisoning effect of CO2 on the reaction. A natural convection loop provided the means for circulating gases past the catalyst and the nitrogen trap in the batch system. Pressure change due to reaction was the criterion used to determine the kinetics. The reactions were studied between 250°C and 310°C, with initial total pressure of approximately 35 torr. The overall order dependency was found to be approximately 1.1, with individual orders of approximately 0.9 and 0.2 for carbon monoxide and oxygen, respectively. The apparent activation energy for the reaction was found to be 15.1 Kcal/mole.","abstract_has_math":false,"creators":["Stone, Charles Joseph"],"institution":"Rice University","degree_name":"Master of Science","degree_level":"Masters","degree_discipline":"Engineering","degree_department":null,"school":null,"contributors":[],"advisors":["Leland, Thomas W."],"committee_chairs":[],"committee_members":[],"year":1970,"date_issued":"1970","date_published":"1970","updated_at":"2026-07-24T04:10:28Z","subjects":[],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/89362","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Leland, Thomas W."]},{"key":"dc:creator","label":"Author","values":["Stone, Charles Joseph"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-04-21T12:02:17Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-04-21T12:02:17Z"]},{"key":"dc:date.issued","label":"Date","values":["1970"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Engineering"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. 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The reactions were studied between 250°C and 310°C, with initial total pressure of approximately 35 torr. The overall order dependency was found to be approximately 1.1, with individual orders of approximately 0.9 and 0.2 for carbon monoxide and oxygen, respectively. The apparent activation energy for the reaction was found to be 15.1 Kcal/mole."]},{"key":"dc:title","label":"Title","values":["The oxidation of carbon monoxide on zinc oxide"]}]}],"canonical_facts":{"dc:contributor.advisor":["Leland, Thomas W."],"dc:creator":["Stone, Charles Joseph"],"dc:date.accessioned":["2016-04-21T12:02:17Z"],"dc:date.available":["2016-04-21T12:02:17Z"],"dc:date.issued":["1970"],"dc:description.abstract":["A study was made of the kinetics of the oxidation of carbon monoxide to form carbon dioxide. The catalyst was high purity zinc oxide. A liquid nitrogen trap was used to remove the product carbon dioxide, thereby virtually eliminating any poisoning effect of CO2 on the reaction. A natural convection loop provided the means for circulating gases past the catalyst and the nitrogen trap in the batch system. Pressure change due to reaction was the criterion used to determine the kinetics. The reactions were studied between 250°C and 310°C, with initial total pressure of approximately 35 torr. The overall order dependency was found to be approximately 1.1, with individual orders of approximately 0.9 and 0.2 for carbon monoxide and oxygen, respectively. The apparent activation energy for the reaction was found to be 15.1 Kcal/mole."],"dc:identifier.uri":["https://hdl.handle.net/1911/89362"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:title":["The oxidation of carbon monoxide on zinc oxide"],"dc:type":["Thesis"],"thesis:degree_discipline":["Engineering"],"thesis:degree_level":["Masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:28Z"}