{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/18435"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/18435","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"The crystal structures of sodium bicarbonate, propionic acid and valeric acid","abstract":"Although Zachariasen was able to determine the gross structure of sodium bicarbonate, his assumptions preclude any conclusions to be drawn concerning the nature of the carbonate group itself. It is therefore the purpose of this paper to reinvestigate the sodium bicarbonate structure employing modern Weissenberg photography and least squares refinement techniques with particular emphasis placed on the determination of the carbonate group configuration. Zachariasen&apos;s parameters and bond distances will appear in conjunction with the results reported here to facilitate ease of comparison.","abstract_html":"Although Zachariasen was able to determine the gross structure of sodium bicarbonate, his assumptions preclude any conclusions to be drawn concerning the nature of the carbonate group itself. It is therefore the purpose of this paper to reinvestigate the sodium bicarbonate structure employing modern Weissenberg photography and least squares refinement techniques with particular emphasis placed on the determination of the carbonate group configuration. Zachariasen&amp;apos;s parameters and bond distances will appear in conjunction with the results reported here to facilitate ease of comparison.","abstract_has_math":false,"creators":["Scheuerman, Ronald F."],"institution":"Rice University","degree_name":"Doctor of Philosophy","degree_level":"Doctoral","degree_discipline":"Natural Sciences","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1961,"date_issued":"1961","date_published":"1961","updated_at":"2026-07-24T04:10:37Z","subjects":["Condensed matter physics"],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/18435","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Scheuerman, Ronald F."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2007-08-21T01:07:40Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2007-08-21T01:07:40Z"]},{"key":"dc:date.issued","label":"Date","values":["1961"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Natural Sciences"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Doctoral"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Doctor of Philosophy"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Condensed matter physics"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/1911/18435"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Although Zachariasen was able to determine the gross structure of sodium bicarbonate, his assumptions preclude any conclusions to be drawn concerning the nature of the carbonate group itself. It is therefore the purpose of this paper to reinvestigate the sodium bicarbonate structure employing modern Weissenberg photography and least squares refinement techniques with particular emphasis placed on the determination of the carbonate group configuration. Zachariasen&apos;s parameters and bond distances will appear in conjunction with the results reported here to facilitate ease of comparison."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["The crystal structures of sodium bicarbonate, propionic acid and valeric acid"]}]}],"canonical_facts":{"dc:creator":["Scheuerman, Ronald F."],"dc:date.accessioned":["2007-08-21T01:07:40Z"],"dc:date.available":["2007-08-21T01:07:40Z"],"dc:date.issued":["1961"],"dc:description.abstract":["Although Zachariasen was able to determine the gross structure of sodium bicarbonate, his assumptions preclude any conclusions to be drawn concerning the nature of the carbonate group itself. It is therefore the purpose of this paper to reinvestigate the sodium bicarbonate structure employing modern Weissenberg photography and least squares refinement techniques with particular emphasis placed on the determination of the carbonate group configuration. Zachariasen&apos;s parameters and bond distances will appear in conjunction with the results reported here to facilitate ease of comparison."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["https://hdl.handle.net/1911/18435"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:subject":["Condensed matter physics"],"dc:title":["The crystal structures of sodium bicarbonate, propionic acid and valeric acid"],"dc:type":["Thesis"],"thesis:degree_discipline":["Natural Sciences"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Doctor of Philosophy"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:37Z"}