Color center laser kinetic spectroscopy: Evidence for quasilinearity of HCCN

The C-H stretching fundamental of the free radical HCCN has been investigated under high resolution using infrared kinetic spectroscopy. This transient molecule was produced by the flash photolysis of dibromoacetonitrile (Br$\sb2$HCCN) at 193 nm and its transient infrared absorption spectrum probed using a color center laser. Spectra of the molecule were collected between 3182 and 3274 cm$\sp{-1}$. The rotational analysis of the $\nu\sb1$ fundamental places its origin at 3246.657 cm$\sp{-1}$. Four hot bands associated with the bending vibrations have been observed; the vibrational and rotational assignment of three of these bands $\nu\sb1 + \nu\sb5 - \nu\sb5$, $\nu\sb1 + \nu\sb4 - \nu\sb4$, and $\nu\sb1 + 2\nu\sb5\sp{\pm 2} - 2\nu\sb5\sp{\pm 2}$ is definite. The $\nu\sb5$ energy was obtained by measuring the intensity of a line of the $\nu\sb1 + \nu\sb5 - \nu\sb5$ band relative to one of the fundamental and calculating the energy assuming a room temperature Boltzmann distribution. A comparison of this energy with that of quasilinear fulminic acid, HCNO, and with theoretical calculations suggests a similar floppy HCX bending potential.

Name thesis:degree_name

Master of Arts

Level thesis:degree_level

Masters

Discipline thesis:degree_discipline

Natural Sciences

Grantor

Rice University

Year dc:date.issued

1994

Author dc:creator

• Farhat, Shahla Khan

Advisor dc:contributor.advisor

• Curl, Robert F., Jr.

• Physical chemistry

Statement dc:rights

• Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder.

Language dc:language.iso

eng

Handle dc:identifier.uri

https://hdl.handle.net/1911/17050

OAI identifier oai:identifier

oai:repository.rice.edu:1911/17050