{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/15780"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/15780","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"ACTIVATION OF AMMONIA, SECONDARY, AND TERTIARY AMINES BY GROUP IIA AND FIRST ROW MIDDLE AND LATE TRANSITION METAL ATOMS AND CLUSTERS","abstract":"Activation of ammonia and amines occurs during metal vapor synthesis at cryogenic temperatures. The Group IIA metal atoms: magnesium, calcium, strontium, and barium, and the transition metal atoms: chromium, manganese, iron, cobalt, nickel, and zinc react with amines and ammonia. Copper metal atoms do not react. Methane and hydrogen are evoved during warming of the Mn/(CH(,3))(,3)N matrix; methane is evolved during warming of the Mn/(CH(,3)CH(,2))(,3)N matrix. Hydrolysis of the cocondensates yields saturated and unsaturated hydrocarbons, and in some cases, hydrogen is formed. The reaction of certain cocondensates with unsaturated compounds yields hydrogenated products.","abstract_html":"Activation of ammonia and amines occurs during metal vapor synthesis at cryogenic temperatures. The Group IIA metal atoms: magnesium, calcium, strontium, and barium, and the transition metal atoms: chromium, manganese, iron, cobalt, nickel, and zinc react with amines and ammonia. Copper metal atoms do not react. Methane and hydrogen are evoved during warming of the Mn/(CH(,3))(,3)N matrix; methane is evolved during warming of the Mn/(CH(,3)CH(,2))(,3)N matrix. Hydrolysis of the cocondensates yields saturated and unsaturated hydrocarbons, and in some cases, hydrogen is formed. The reaction of certain cocondensates with unsaturated compounds yields hydrogenated products.","abstract_has_math":false,"creators":["RAO, NANCY ANN"],"institution":"Rice University","degree_name":"Doctor of Philosophy","degree_level":"Doctoral","degree_discipline":"Natural Sciences","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1983,"date_issued":"1983","date_published":"1983","updated_at":"2026-07-24T04:10:15Z","subjects":["Organic chemistry"],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/15780","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["RAO, NANCY ANN"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2007-05-09T19:33:32Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2007-05-09T19:33:32Z"]},{"key":"dc:date.issued","label":"Date","values":["1983"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Natural Sciences"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Doctoral"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Doctor of Philosophy"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Organic chemistry"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/1911/15780"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Activation of ammonia and amines occurs during metal vapor synthesis at cryogenic temperatures. The Group IIA metal atoms: magnesium, calcium, strontium, and barium, and the transition metal atoms: chromium, manganese, iron, cobalt, nickel, and zinc react with amines and ammonia. Copper metal atoms do not react. Methane and hydrogen are evoved during warming of the Mn/(CH(,3))(,3)N matrix; methane is evolved during warming of the Mn/(CH(,3)CH(,2))(,3)N matrix. Hydrolysis of the cocondensates yields saturated and unsaturated hydrocarbons, and in some cases, hydrogen is formed. The reaction of certain cocondensates with unsaturated compounds yields hydrogenated products."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["ACTIVATION OF AMMONIA, SECONDARY, AND TERTIARY AMINES BY GROUP IIA AND FIRST ROW MIDDLE AND LATE TRANSITION METAL ATOMS AND CLUSTERS"]}]}],"canonical_facts":{"dc:creator":["RAO, NANCY ANN"],"dc:date.accessioned":["2007-05-09T19:33:32Z"],"dc:date.available":["2007-05-09T19:33:32Z"],"dc:date.issued":["1983"],"dc:description.abstract":["Activation of ammonia and amines occurs during metal vapor synthesis at cryogenic temperatures. The Group IIA metal atoms: magnesium, calcium, strontium, and barium, and the transition metal atoms: chromium, manganese, iron, cobalt, nickel, and zinc react with amines and ammonia. Copper metal atoms do not react. Methane and hydrogen are evoved during warming of the Mn/(CH(,3))(,3)N matrix; methane is evolved during warming of the Mn/(CH(,3)CH(,2))(,3)N matrix. Hydrolysis of the cocondensates yields saturated and unsaturated hydrocarbons, and in some cases, hydrogen is formed. The reaction of certain cocondensates with unsaturated compounds yields hydrogenated products."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["https://hdl.handle.net/1911/15780"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:subject":["Organic chemistry"],"dc:title":["ACTIVATION OF AMMONIA, SECONDARY, AND TERTIARY AMINES BY GROUP IIA AND FIRST ROW MIDDLE AND LATE TRANSITION METAL ATOMS AND CLUSTERS"],"dc:type":["Thesis"],"thesis:degree_discipline":["Natural Sciences"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Doctor of Philosophy"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:15Z"}