{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/106017"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/106017","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"Alkylation of Boron Nitride Nanomaterials using Reductive Conditions","abstract":"Boron nitride nanomaterials possess an unparalleled combination of properties: their mechanic properties are superior to that of steel, their thermal conductivity is comparable to that of copper, their band gap is that of an insulating material, and their chemical and thermal stability is remarkable. Researchers anticipate that this unique set of properties will have applications in a wide array of fields. However, boron nitride nanomaterials are not perfect. It is their poor dispersibility in solvents and their chemical inertness that have frustrated their comprehensive utilization. The ability to chemically modify these nanostructures could open the door to tune their properties and expand their compatibility with solvents. Therefore, this thesis investigates an unexplored chemical tool for boron nitride nanomaterials: the Billups-Birch reduction.","abstract_html":"Boron nitride nanomaterials possess an unparalleled combination of properties: their mechanic properties are superior to that of steel, their thermal conductivity is comparable to that of copper, their band gap is that of an insulating material, and their chemical and thermal stability is remarkable. Researchers anticipate that this unique set of properties will have applications in a wide array of fields. However, boron nitride nanomaterials are not perfect. It is their poor dispersibility in solvents and their chemical inertness that have frustrated their comprehensive utilization. The ability to chemically modify these nanostructures could open the door to tune their properties and expand their compatibility with solvents. Therefore, this thesis investigates an unexplored chemical tool for boron nitride nanomaterials: the Billups-Birch reduction.","abstract_has_math":false,"creators":["de los Reyes Berrones, Carlos Alberto"],"institution":"Rice University","degree_name":"Doctor of Philosophy","degree_level":"Doctoral","degree_discipline":"Natural Sciences","degree_department":null,"school":null,"contributors":[],"advisors":["Martí, Angel A"],"committee_chairs":[],"committee_members":[],"year":2019,"date_issued":"2019-04-17","date_published":"2019-04-17","updated_at":"2026-07-24T04:10:39Z","subjects":["Boron nitride nanomaterials","boron nitride nanotubes","hexagonal boron nitride","Billups-Birch reaction","alkylation","functionalization"],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/106017","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Martí, Angel A"]},{"key":"dc:creator","label":"Author","values":["de los Reyes Berrones, Carlos Alberto"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2019-05-17T19:18:41Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2019-11-01T05:01:21Z"]},{"key":"dc:date.issued","label":"Date","values":["2019-04-17"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Natural Sciences"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Doctoral"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Doctor of Philosophy"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Boron nitride nanomaterials","boron nitride nanotubes","hexagonal boron nitride","Billups-Birch reaction","alkylation","functionalization"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. 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It is their poor dispersibility in solvents and their chemical inertness that have frustrated their comprehensive utilization. The ability to chemically modify these nanostructures could open the door to tune their properties and expand their compatibility with solvents. Therefore, this thesis investigates an unexplored chemical tool for boron nitride nanomaterials: the Billups-Birch reduction."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Alkylation of Boron Nitride Nanomaterials using Reductive Conditions"]}]}],"canonical_facts":{"dc:contributor.advisor":["Martí, Angel A"],"dc:creator":["de los Reyes Berrones, Carlos Alberto"],"dc:date.accessioned":["2019-05-17T19:18:41Z"],"dc:date.available":["2019-11-01T05:01:21Z"],"dc:date.issued":["2019-04-17"],"dc:description.abstract":["Boron nitride nanomaterials possess an unparalleled combination of properties: their mechanic properties are superior to that of steel, their thermal conductivity is comparable to that of copper, their band gap is that of an insulating material, and their chemical and thermal stability is remarkable. Researchers anticipate that this unique set of properties will have applications in a wide array of fields. However, boron nitride nanomaterials are not perfect. It is their poor dispersibility in solvents and their chemical inertness that have frustrated their comprehensive utilization. The ability to chemically modify these nanostructures could open the door to tune their properties and expand their compatibility with solvents. Therefore, this thesis investigates an unexplored chemical tool for boron nitride nanomaterials: the Billups-Birch reduction."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["https://hdl.handle.net/1911/106017"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:subject":["Boron nitride nanomaterials","boron nitride nanotubes","hexagonal boron nitride","Billups-Birch reaction","alkylation","functionalization"],"dc:title":["Alkylation of Boron Nitride Nanomaterials using Reductive Conditions"],"dc:type":["Thesis"],"thesis:degree_discipline":["Natural Sciences"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Doctor of Philosophy"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:39Z"}