{"id":{"repo_id":"rice","oai_identifier":"oai:repository.rice.edu:1911/104504"},"canonical_url":"https://search.dev.ndltd.org/etd/rice/oai:repository.rice.edu:1911/104504","repository":{"repo_id":"rice","name":"Rice University","base_url":"https://repository.rice.edu/server/oai/request"},"display":{"title":"A carbon-13 nuclear magnetic resonance study of a series of cyclohexanol amines","abstract":"A carbon-13 nuclear magnetic resonance spectral investigation of the monosubstituted-butylcyclohexyl alcohols, amines, and ammonium salts was undertaken and the resultant correlations were extended to a series of eight b-butylcyclohexanol amines and their hydrochloride salts. Among the effects examined were the substituent parameters of the mono- and difunctionalized t-butylcyclohexanes and the perturbations of the chemical shifts due to amine protonation in the cyclohexyl amines and the amino alcohols. An anomalous behavior was observed for the trans-2-ammonium salt.","abstract_html":"A carbon-13 nuclear magnetic resonance spectral investigation of the monosubstituted-butylcyclohexyl alcohols, amines, and ammonium salts was undertaken and the resultant correlations were extended to a series of eight b-butylcyclohexanol amines and their hydrochloride salts. Among the effects examined were the substituent parameters of the mono- and difunctionalized t-butylcyclohexanes and the perturbations of the chemical shifts due to amine protonation in the cyclohexyl amines and the amino alcohols. An anomalous behavior was observed for the trans-2-ammonium salt.","abstract_has_math":false,"creators":["Slovin, Eliot Mark"],"institution":"Rice University","degree_name":"Master of Arts","degree_level":"Masters","degree_discipline":"Natural Sciences","degree_department":null,"school":null,"contributors":[],"advisors":["Wenkert, Ernest"],"committee_chairs":[],"committee_members":[],"year":1976,"date_issued":"1976","date_published":"1976","updated_at":"2026-07-24T04:10:28Z","subjects":[],"languages":["eng"],"rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/1911/104504","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Wenkert, Ernest"]},{"key":"dc:creator","label":"Author","values":["Slovin, Eliot Mark"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2018-12-18T21:24:23Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2018-12-18T21:24:23Z"]},{"key":"dc:date.issued","label":"Date","values":["1976"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Natural Sciences"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Arts"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Rice University"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/1911/104504"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["A carbon-13 nuclear magnetic resonance spectral investigation of the monosubstituted-butylcyclohexyl alcohols, amines, and ammonium salts was undertaken and the resultant correlations were extended to a series of eight b-butylcyclohexanol amines and their hydrochloride salts. Among the effects examined were the substituent parameters of the mono- and difunctionalized t-butylcyclohexanes and the perturbations of the chemical shifts due to amine protonation in the cyclohexyl amines and the amino alcohols. An anomalous behavior was observed for the trans-2-ammonium salt."]},{"key":"dc:title","label":"Title","values":["A carbon-13 nuclear magnetic resonance study of a series of cyclohexanol amines"]}]}],"canonical_facts":{"dc:contributor.advisor":["Wenkert, Ernest"],"dc:creator":["Slovin, Eliot Mark"],"dc:date.accessioned":["2018-12-18T21:24:23Z"],"dc:date.available":["2018-12-18T21:24:23Z"],"dc:date.issued":["1976"],"dc:description.abstract":["A carbon-13 nuclear magnetic resonance spectral investigation of the monosubstituted-butylcyclohexyl alcohols, amines, and ammonium salts was undertaken and the resultant correlations were extended to a series of eight b-butylcyclohexanol amines and their hydrochloride salts. Among the effects examined were the substituent parameters of the mono- and difunctionalized t-butylcyclohexanes and the perturbations of the chemical shifts due to amine protonation in the cyclohexyl amines and the amino alcohols. An anomalous behavior was observed for the trans-2-ammonium salt."],"dc:identifier.uri":["https://hdl.handle.net/1911/104504"],"dc:language.iso":["eng"],"dc:rights":["Copyright is held by the author, unless otherwise indicated. Permission to reuse, publish, or reproduce the work beyond the bounds of fair use or other exemptions to copyright law must be obtained from the copyright holder."],"dc:title":["A carbon-13 nuclear magnetic resonance study of a series of cyclohexanol amines"],"dc:type":["Thesis"],"thesis:degree_discipline":["Natural Sciences"],"thesis:degree_level":["Masters"],"thesis:degree_name":["Master of Arts"],"thesis:institution_name":["Rice University"]},"updated_at":"2026-07-24T04:10:28Z"}