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Queens University

CO2-Triggered Switchable Solvent Systems and Their Applications

Abstract

dc:description.abstract

This thesis begins with the introduction of solvents and their classification. The two solvent system studied here are switchable polarity solvents (SPS). A switchable polarity solvent is a liquid where its polarity can change between two forms by a trigger. These two solvent systems have several similar characteristics. First, they both require CO2 as the switching agent, which can be switched back by its removal with heat or N2. The first project is the continuation of previous work with using an amidine and alcohol mixtures as a switchable polarity solvent. The second project was the development of a new switchable polarity solvent that is based on the reaction of a secondary amine with CO2. Both solvent systems are fully characterized by many analytical techniques and examples of applications in chemical reaction and separation are outlined. The final project involves using these solvent systems, among others, in the separation of soybean oil. The aim was to use SPS technology to extract soybean oil from the bean flakes, and then separate the oil from the extracting solvent.

Degree

thesis:*
Department dc:contributor.department
Chemistry
Year dc:date.issued
2008

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Phan, Lam
Advisor dc:contributor.supervisor
  • Jessop, Philip G.

Subjects

dc:subject × 2

Rights

Language dc:language.iso
eng

Identifiers

dc:identifier.*
Handle dc:identifier.uri
http://hdl.handle.net/1974/1563
OAI identifier oai:identifier
oai:queensu.scholaris.ca:1974/1563

Chain of custody

source
Harvested from
Queens University
Base URL
qspace.library.queensu.ca/server/oai/request
Last updated
2026-07-27
Source record
OAI-PMH GetRecord
citation

Phan, Lam. CO2-Triggered Switchable Solvent Systems and Their Applications. 2008. http://hdl.handle.net/1974/1563