{"id":{"repo_id":"ohiolink","oai_identifier":"oai:etd.ohiolink.edu:wright1357925302"},"canonical_url":"https://search.dev.ndltd.org/etd/ohiolink/oai:etd.ohiolink.edu:wright1357925302","repository":{"repo_id":"ohiolink","name":"OhioLINK","base_url":"https://etd.ohiolink.edu/acprod/odb_etd/ws/oai/oai"},"display":{"title":"Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode","abstract":"Electrochemical properties of [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 and [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3] in 1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)-imide ionic liquid was investigated. Cyclic voltammograms using a Platinum electrode indicated deposition had occurred for the [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 metal cluster but had not for the polynuclear complex [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3]. Constant potential electrolysis of -1.23 V using a platinum foil electrode was performed. Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred.","abstract_html":"Electrochemical properties of [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 and [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3] in 1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)-imide ionic liquid was investigated. Cyclic voltammograms using a Platinum electrode indicated deposition had occurred for the [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 metal cluster but had not for the polynuclear complex [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3]. Constant potential electrolysis of -1.23 V using a platinum foil electrode was performed. Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred.","abstract_has_math":false,"creators":["Frock, Lynn Renee"],"institution":"Wright State University","degree_name":"Master of Science (MS)","degree_level":"masters","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Katovic, Vladimir","Grossie, David"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2012,"date_issued":"2012","date_published":"2012","updated_at":"2026-07-24T03:36:39Z","subjects":["Analytical Chemistry","Energy","Molybdenum electrodeposition"],"languages":["English"],"rights":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Katovic, Vladimir","Grossie, David"]},{"key":"dc:creator","label":"Author","values":["Frock, Lynn Renee"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2012"]},{"key":"dc:publisher","label":"Institution","values":["Wright State University / OhioLINK"]},{"key":"dc:type","label":"Dc Type","values":["Electronic Thesis or Dissertation"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (MS)"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Wright State University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Analytical Chemistry","Energy","Molybdenum electrodeposition"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]},{"key":"dc:rights","label":"Dc Rights","values":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. 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Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf","p.72","2.8 MB"]},{"key":"dc:title","label":"Title","values":["Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode"]}]}],"canonical_facts":{"dc:contributor":["Katovic, Vladimir","Grossie, David"],"dc:creator":["Frock, Lynn Renee"],"dc:date":["2012"],"dc:description":["Electrochemical properties of [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 and [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3] in 1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)-imide ionic liquid was investigated. Cyclic voltammograms using a Platinum electrode indicated deposition had occurred for the [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 metal cluster but had not for the polynuclear complex [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3]. Constant potential electrolysis of -1.23 V using a platinum foil electrode was performed. Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred."],"dc:format":["application/pdf","p.72","2.8 MB"],"dc:identifier":["http://rave.ohiolink.edu/etdc/view?acc_num=wright1357925302"],"dc:language":["English"],"dc:publisher":["Wright State University / OhioLINK"],"dc:rights":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws."],"dc:subject":["Analytical Chemistry","Energy","Molybdenum electrodeposition"],"dc:title":["Synthesis and Electrodeposition of Mixed Metal Trinuclear Clusters of Molybdenum and Chromium in Ionic Liquid onto a Platinum Electrode"],"dc:type":["Electronic Thesis or Dissertation"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["masters"],"thesis:degree_name":["Master of Science (MS)"],"thesis:institution_name":["Wright State University"]},"updated_at":"2026-07-24T03:36:39Z"}