{"id":{"repo_id":"ohiolink","oai_identifier":"oai:etd.ohiolink.edu:osu1365595950"},"canonical_url":"https://search.dev.ndltd.org/etd/ohiolink/oai:etd.ohiolink.edu:osu1365595950","repository":{"repo_id":"ohiolink","name":"OhioLINK","base_url":"https://etd.ohiolink.edu/acprod/odb_etd/ws/oai/oai"},"display":{"title":"Rhenium(II) Complexes as Potential materials for Dye Sensitized Solar Cells","abstract":"Tandem dye sensitized solar cells, in which both the anode and cathode are photo sensitive, had been proved to improve the overall efficiency of a DSSC. The compounds [Re(dppe)2Cl2]Cl and [Re(dppe)2O2]ClO4, where dppe is 1,2-bis(diphenylphosphino)ethane, were synthesized as potential materials for the photo cathode in a dye sensitized solar cell. Both compounds are synthesized from the same precursor, [(Bu)4N]2[Re2Cl8], which is sintesized from NaReO4. The compounds were characterized by 1H NMR and ESI-MS.Spectrophotometric measurements were performed for both complexed, founding that both exhibit appreciable emission around 600 nm. A cyclic voltammogram was obtained for the [Re(dppe)2Cl2]Cl complex, and it was determined that the first reduction of this compound is reversible. The preliminary data suggests that the [Re(ddppe)2Cl2]Cl compound may be suitable as a dye for the photo cathode in a tandem DSSC.","abstract_html":"Tandem dye sensitized solar cells, in which both the anode and cathode are photo sensitive, had been proved to improve the overall efficiency of a DSSC. The compounds [Re(dppe)<sub>2</sub>Cl<sub>2</sub>]Cl and [Re(dppe)<sub>2</sub>O<sub>2</sub>]ClO<sub>4</sub>, where dppe is 1,2-bis(diphenylphosphino)ethane, were synthesized as potential materials for the photo cathode in a dye sensitized solar cell. Both compounds are synthesized from the same precursor, [(Bu)<sub>4</sub>N]<sub>2</sub>[Re<sub>2</sub>Cl<sub>8</sub>], which is sintesized from NaReO<sub>4</sub>. The compounds were characterized by <sup>1</sup>H NMR and ESI-MS.Spectrophotometric measurements were performed for both complexed, founding that both exhibit appreciable emission around 600 nm. A cyclic voltammogram was obtained for the [Re(dppe)<sub>2</sub>Cl<sub>2</sub>]Cl complex, and it was determined that the first reduction of this compound is reversible. The preliminary data suggests that the [Re(ddppe)<sub>2</sub>Cl<sub>2</sub>]Cl compound may be suitable as a dye for the photo cathode in a tandem DSSC.","abstract_has_math":false,"creators":["Cussianovich, Ivan Martin"],"institution":"The Ohio State University","degree_name":"Master of Science","degree_level":"masters","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Turro, Claudia"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2013,"date_issued":"2013-07-23","date_published":"2013-07-23","updated_at":"2026-07-24T03:37:31Z","subjects":["Chemistry"],"languages":["English"],"rights":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://rave.ohiolink.edu/etdc/view?acc_num=osu1365595950","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Turro, Claudia"]},{"key":"dc:creator","label":"Author","values":["Cussianovich, Ivan Martin"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2013-07-23"]},{"key":"dc:publisher","label":"Institution","values":["The Ohio State University / OhioLINK"]},{"key":"dc:type","label":"Dc Type","values":["Electronic Thesis or Dissertation"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["The Ohio State University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]},{"key":"dc:rights","label":"Dc Rights","values":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. 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The compounds were characterized by 1H NMR and ESI-MS.Spectrophotometric measurements were performed for both complexed, founding that both exhibit appreciable emission around 600 nm. A cyclic voltammogram was obtained for the [Re(dppe)2Cl2]Cl complex, and it was determined that the first reduction of this compound is reversible. The preliminary data suggests that the [Re(ddppe)2Cl2]Cl compound may be suitable as a dye for the photo cathode in a tandem DSSC."]},{"key":"dc:format","label":"Dc Format","values":["application/pdf","p.40","1. MB"]},{"key":"dc:title","label":"Title","values":["Rhenium(II) Complexes as Potential materials for Dye Sensitized Solar Cells"]}]}],"canonical_facts":{"dc:contributor":["Turro, Claudia"],"dc:creator":["Cussianovich, Ivan Martin"],"dc:date":["2013-07-23"],"dc:description":["Tandem dye sensitized solar cells, in which both the anode and cathode are photo sensitive, had been proved to improve the overall efficiency of a DSSC. The compounds [Re(dppe)2Cl2]Cl and [Re(dppe)2O2]ClO4, where dppe is 1,2-bis(diphenylphosphino)ethane, were synthesized as potential materials for the photo cathode in a dye sensitized solar cell. Both compounds are synthesized from the same precursor, [(Bu)4N]2[Re2Cl8], which is sintesized from NaReO4. The compounds were characterized by 1H NMR and ESI-MS.Spectrophotometric measurements were performed for both complexed, founding that both exhibit appreciable emission around 600 nm. A cyclic voltammogram was obtained for the [Re(dppe)2Cl2]Cl complex, and it was determined that the first reduction of this compound is reversible. The preliminary data suggests that the [Re(ddppe)2Cl2]Cl compound may be suitable as a dye for the photo cathode in a tandem DSSC."],"dc:format":["application/pdf","p.40","1. MB"],"dc:identifier":["http://rave.ohiolink.edu/etdc/view?acc_num=osu1365595950"],"dc:language":["English"],"dc:publisher":["The Ohio State University / OhioLINK"],"dc:rights":["unrestricted","This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws."],"dc:subject":["Chemistry"],"dc:title":["Rhenium(II) Complexes as Potential materials for Dye Sensitized Solar Cells"],"dc:type":["Electronic Thesis or Dissertation"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["masters"],"thesis:degree_name":["Master of Science"],"thesis:institution_name":["The Ohio State University"]},"updated_at":"2026-07-24T03:37:31Z"}