{"id":{"repo_id":"nus","oai_identifier":"oai:scholarbank.nus.edu.sg:10635/135448"},"canonical_url":"https://search.dev.ndltd.org/etd/nus/oai:scholarbank.nus.edu.sg:10635/135448","repository":{"repo_id":"nus","name":"National University of Singapore","base_url":"https://scholarbank.nus.edu.sg/oai/request"},"display":{"title":"NEW MULTIMETALLIC ASSEMBLIES AS PHOTOLUMINESCENT MATERIALS","abstract":"During the last few decades significant progress has been made in the area of supramolecular polymers, where monomers are held together by non-covalent interactions. In particular, the formation of macromolecular assemblies by employing a metal-ion induced selfassembly process in solution is of significant interest. These supramolecular metallo-polymers combine common features of traditional covalently-bound polymers with the unique characteristics introduced by metal ions. So far, the research in this area has mainly focused on the metal-induced self-assembly of d-block metals and ditopic tridentate organic ligands. The overall aim of this project was to extend the knowledge in this area to Ln(III)-containing soluble supramolecular metallo-polymers and to study their overall photophysical properties.","abstract_html":"During the last few decades significant progress has been made in the area of supramolecular polymers, where monomers are held together by non-covalent interactions. In particular, the formation of macromolecular assemblies by employing a metal-ion induced selfassembly process in solution is of significant interest. These supramolecular metallo-polymers combine common features of traditional covalently-bound polymers with the unique characteristics introduced by metal ions. So far, the research in this area has mainly focused on the metal-induced self-assembly of d-block metals and ditopic tridentate organic ligands. 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In particular, the formation of macromolecular assemblies by employing a metal-ion induced selfassembly process in solution is of significant interest. These supramolecular metallo-polymers combine common features of traditional covalently-bound polymers with the unique characteristics introduced by metal ions. So far, the research in this area has mainly focused on the metal-induced self-assembly of d-block metals and ditopic tridentate organic ligands. 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These supramolecular metallo-polymers combine common features of traditional covalently-bound polymers with the unique characteristics introduced by metal ions. So far, the research in this area has mainly focused on the metal-induced self-assembly of d-block metals and ditopic tridentate organic ligands. The overall aim of this project was to extend the knowledge in this area to Ln(III)-containing soluble supramolecular metallo-polymers and to study their overall photophysical properties."],"dc:format.checksum.md5":["f129470cc9d9200d8bc72850834e2087","2357534865fe7959d451685e88ac193f"],"dc:identifier.uri":["https://scholarbank.nus.edu.sg/bitstreams/8d942ff2-c90d-4386-9469-86038c1edfd5/download"],"dc:relation.isreferencedby":["https://scholarbank.nus.edu.sg/handle/10635/135448"],"dc:subject":["New Multimetallic Assemblies as Photoluminescent Materials"],"dc:title":["NEW MULTIMETALLIC ASSEMBLIES AS PHOTOLUMINESCENT MATERIALS"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T03:31:26Z"}