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The impact and fate of aqueous sodium nitrate on hydrocarbon flames

Abstract

dc:description.abstract

This study examined the impact and fate of sodium (fed as an aqueous nitrate solution) in fuel-rich methane/air and methane/methyl chloride/air flames as a function of equivalence ratios that experienced diffusion of air from the surroundings. The flames were stabilized on a slotted, uncooled burner. The data set was divided into profiles of relative sodium atom concentrations, temperatures, and selected stable species concentrations. The flames were simulated using a modified version of the Sandia FORTRAN program for modeling steady laminar one-dimensional premixed flames complete with detailed mechanisms. The results showed that maximum sodium atom concentration in the flame is decreased by an increase in equivalence ratio as well as an increase in chlorine loading. In addition, the location of maximum sodium atom concentration is shifted to a higher height above burner as the equivalence ratio is increased.

Degree

thesis:*
Name thesis:degree_name
Doctor of Philosophy in Chemical Engineering - (Ph.D.)
Discipline thesis:degree_discipline
Chemical Engineering, Chemistry and Environmental Science
Year
2000

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Flynn, Ann Marie
Contributors dc:contributor
  • Robert Benedict Barat
  • Joseph W. Bozzelli
  • Barbara B. Kebbekus

Subjects

dc:subject × 5

Identifiers

dc:identifier.*
Repository record dc:identifier
https://digitalcommons.njit.edu/dissertations/401
OAI identifier oai:identifier
oai:digitalcommons.njit.edu:dissertations-1456

Chain of custody

source
Harvested from
NJIT
Base URL
digitalcommons.njit.edu/do/oai/
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
citation

Flynn, Ann Marie. The impact and fate of aqueous sodium nitrate on hydrocarbon flames. 2000. https://digitalcommons.njit.edu/dissertations/401