{"id":{"repo_id":"must-thes","oai_identifier":"oai:scholarsmine.mst.edu:doctoral_dissertations-3205"},"canonical_url":"https://search.dev.ndltd.org/etd/must-thes/oai:scholarsmine.mst.edu:doctoral_dissertations-3205","repository":{"repo_id":"must-thes","name":"Missouri University of Science and Technology","base_url":"https://scholarsmine.mst.edu/do/oai/"},"display":{"title":"Liquid extraction with single droplets-effect of chemical reaction","abstract":"\"The circulating drop mass transport model based on Hadamard's dispersed phase stream function was solved numerically to account for a solute diffusing into a droplet and undergoing a first order irreversible reaction with the drop medium for the case where the continuous phase resistance to solute transport is negligible ... Experimental data were obtained for a system which consisted of 2-chloro-2-methylpropane (t-butyl chloride) diffusing from a benzene continuous phase into falling water droplets and undergoing a first order irreversible reaction with the water droplets ... The experimental solute transport rates were a factor of 7 to 10 greater than those predicted by the circulating drop model (or Penetration theory) and a factor of 2.5 to 3 greater than those predicted by the Handlos and Baron model ... From visual observations of a stationary droplet in contact with the continuous phase during the transfer process, it was concluded that the deviation between the theoretical models and the experimental data was due to a special type of interfacial motion not usually observed when two liquids are in contact\"--Abstract, page i-ii.","abstract_html":""The circulating drop mass transport model based on Hadamard's dispersed phase stream function was solved numerically to account for a solute diffusing into a droplet and undergoing a first order irreversible reaction with the drop medium for the case where the continuous phase resistance to solute transport is negligible ... Experimental data were obtained for a system which consisted of 2-chloro-2-methylpropane (t-butyl chloride) diffusing from a benzene continuous phase into falling water droplets and undergoing a first order irreversible reaction with the water droplets ... The experimental solute transport rates were a factor of 7 to 10 greater than those predicted by the circulating drop model (or Penetration theory) and a factor of 2.5 to 3 greater than those predicted by the Handlos and Baron model ... From visual observations of a stationary droplet in contact with the continuous phase during the transfer process, it was concluded that the deviation between the theoretical models and the experimental data was due to a special type of interfacial motion not usually observed when two liquids are in contact"--Abstract, page i-ii.","abstract_has_math":false,"creators":["Andoe, William Victor"],"institution":"University of Missouri at Rolla","degree_name":"Ph. D. in Chemical Engineering","degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2016,"date_issued":"2016-02-10T08:00:00Z","date_published":"2016-02-10T08:00:00Z","updated_at":"2026-07-24T03:20:02Z","subjects":["Chemical Engineering"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://scholarsmine.mst.edu/doctoral_dissertations/2203","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Andoe, William Victor"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2016-02-10T08:00:00Z"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation - Open Access"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph. D. in Chemical Engineering"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Missouri at Rolla"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemical Engineering"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://scholarsmine.mst.edu/doctoral_dissertations/2203"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["\"The circulating drop mass transport model based on Hadamard's dispersed phase stream function was solved numerically to account for a solute diffusing into a droplet and undergoing a first order irreversible reaction with the drop medium for the case where the continuous phase resistance to solute transport is negligible ... Experimental data were obtained for a system which consisted of 2-chloro-2-methylpropane (t-butyl chloride) diffusing from a benzene continuous phase into falling water droplets and undergoing a first order irreversible reaction with the water droplets ... The experimental solute transport rates were a factor of 7 to 10 greater than those predicted by the circulating drop model (or Penetration theory) and a factor of 2.5 to 3 greater than those predicted by the Handlos and Baron model ... From visual observations of a stationary droplet in contact with the continuous phase during the transfer process, it was concluded that the deviation between the theoretical models and the experimental data was due to a special type of interfacial motion not usually observed when two liquids are in contact\"--Abstract, page i-ii."]},{"key":"dc:title","label":"Title","values":["Liquid extraction with single droplets-effect of chemical reaction"]}]}],"canonical_facts":{"dc:creator":["Andoe, William Victor"],"dc:date.available":["2016-02-10T08:00:00Z"],"dc:description.abstract":["\"The circulating drop mass transport model based on Hadamard's dispersed phase stream function was solved numerically to account for a solute diffusing into a droplet and undergoing a first order irreversible reaction with the drop medium for the case where the continuous phase resistance to solute transport is negligible ... Experimental data were obtained for a system which consisted of 2-chloro-2-methylpropane (t-butyl chloride) diffusing from a benzene continuous phase into falling water droplets and undergoing a first order irreversible reaction with the water droplets ... The experimental solute transport rates were a factor of 7 to 10 greater than those predicted by the circulating drop model (or Penetration theory) and a factor of 2.5 to 3 greater than those predicted by the Handlos and Baron model ... From visual observations of a stationary droplet in contact with the continuous phase during the transfer process, it was concluded that the deviation between the theoretical models and the experimental data was due to a special type of interfacial motion not usually observed when two liquids are in contact\"--Abstract, page i-ii."],"dc:identifier":["https://scholarsmine.mst.edu/doctoral_dissertations/2203"],"dc:subject":["Chemical Engineering"],"dc:title":["Liquid extraction with single droplets-effect of chemical reaction"],"dc:type":["Dissertation - Open Access"],"thesis:degree_name":["Ph. D. in Chemical Engineering"],"thesis:institution_name":["University of Missouri at Rolla"]},"updated_at":"2026-07-24T03:20:02Z"}