{"id":{"repo_id":"must-thes","oai_identifier":"oai:scholarsmine.mst.edu:doctoral_dissertations-2725"},"canonical_url":"https://search.dev.ndltd.org/etd/must-thes/oai:scholarsmine.mst.edu:doctoral_dissertations-2725","repository":{"repo_id":"must-thes","name":"Missouri University of Science and Technology","base_url":"https://scholarsmine.mst.edu/do/oai/"},"display":{"title":"Synthesis and characterization of metal reagents mediating C-X activation (X=Cl, H) of hydrocarbons","abstract":"\"This thesis develops methodology for the activation of C-X (X=H, Cl) bonds by transition metals. 2/4-Substituted alkyl pyridines such as cyclohexyl, adamantyl, hydroxyethyl and hydroxymethyl pyridines have been synthesized in moderate to good yields using [Fe<sup>II</sup> (Pic)₂(Py)₂] as a catalyst in pyridine/acetic acid under Gif conditions. The substrates used are alkanes, alcohols and alkyl iodides\"--Abstract, page iii.","abstract_html":"&quot;This thesis develops methodology for the activation of C-X (X=H, Cl) bonds by transition metals. 2/4-Substituted alkyl pyridines such as cyclohexyl, adamantyl, hydroxyethyl and hydroxymethyl pyridines have been synthesized in moderate to good yields using [Fe&lt;sup&gt;II&lt;/sup&gt; (Pic)₂(Py)₂] as a catalyst in pyridine/acetic acid under Gif conditions. The substrates used are alkanes, alcohols and alkyl iodides&quot;--Abstract, page iii.","abstract_has_math":false,"creators":["Pinnapareddy, Devender"],"institution":"University of Missouri--Rolla","degree_name":"Ph. D. in Chemistry","degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2016,"date_issued":"2016-02-10T08:00:00Z","date_published":"2016-02-10T08:00:00Z","updated_at":"2026-07-24T03:19:04Z","subjects":["Oxidation of hydrocarbons","Reductive dechlorinations","Chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://scholarsmine.mst.edu/doctoral_dissertations/1723","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Pinnapareddy, Devender"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2016-02-10T08:00:00Z"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation - Citation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph. D. in Chemistry"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Missouri--Rolla"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Oxidation of hydrocarbons","Reductive dechlorinations","Chemistry"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://scholarsmine.mst.edu/doctoral_dissertations/1723"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["\"This thesis develops methodology for the activation of C-X (X=H, Cl) bonds by transition metals. 2/4-Substituted alkyl pyridines such as cyclohexyl, adamantyl, hydroxyethyl and hydroxymethyl pyridines have been synthesized in moderate to good yields using [Fe<sup>II</sup> (Pic)₂(Py)₂] as a catalyst in pyridine/acetic acid under Gif conditions. The substrates used are alkanes, alcohols and alkyl iodides\"--Abstract, page iii."]},{"key":"dc:title","label":"Title","values":["Synthesis and characterization of metal reagents mediating C-X activation (X=Cl, H) of hydrocarbons"]}]}],"canonical_facts":{"dc:creator":["Pinnapareddy, Devender"],"dc:date.available":["2016-02-10T08:00:00Z"],"dc:description.abstract":["\"This thesis develops methodology for the activation of C-X (X=H, Cl) bonds by transition metals. 2/4-Substituted alkyl pyridines such as cyclohexyl, adamantyl, hydroxyethyl and hydroxymethyl pyridines have been synthesized in moderate to good yields using [Fe<sup>II</sup> (Pic)₂(Py)₂] as a catalyst in pyridine/acetic acid under Gif conditions. The substrates used are alkanes, alcohols and alkyl iodides\"--Abstract, page iii."],"dc:identifier":["https://scholarsmine.mst.edu/doctoral_dissertations/1723"],"dc:subject":["Oxidation of hydrocarbons","Reductive dechlorinations","Chemistry"],"dc:title":["Synthesis and characterization of metal reagents mediating C-X activation (X=Cl, H) of hydrocarbons"],"dc:type":["Dissertation - Citation"],"thesis:degree_name":["Ph. D. in Chemistry"],"thesis:institution_name":["University of Missouri--Rolla"]},"updated_at":"2026-07-24T03:19:04Z"}