{"id":{"repo_id":"mo-state","oai_identifier":"oai:bearworks.missouristate.edu:theses-1362"},"canonical_url":"https://search.dev.ndltd.org/etd/mo-state/oai:bearworks.missouristate.edu:theses-1362","repository":{"repo_id":"mo-state","name":"Missouri State University","base_url":"https://bearworks.missouristate.edu/do/oai/"},"display":{"title":"Study of 4(E)-Trans-6, 7-Epoxy-2, 2-Dimethyl-4-Decen-3-One","abstract":"Hepoxilins are a group of compounds which are biologically active in the body. One of the hepoxilins is vital in the release of insulin. The sites that metabolism chemistry of the hepoxilin molecule takes place will be investigated using a model compound. The model compound, 4(E)-trans-6,7-epoxy-2,2-dimethly-4-decen-3-one, will be synthesized using a Witting reaction. Molecular orbital calculations will be performed to predict reactivity, infrared spectra, and optimized structure. The phosphoranylidene used will by synthesized by reacting 1-bromo-3,3-dimethyl-2-butanone with triphenylphosphine. Then the reactive sities will be tested using phenyllithium.","abstract_html":"Hepoxilins are a group of compounds which are biologically active in the body. One of the hepoxilins is vital in the release of insulin. The sites that metabolism chemistry of the hepoxilin molecule takes place will be investigated using a model compound. The model compound, 4(E)-trans-6,7-epoxy-2,2-dimethly-4-decen-3-one, will be synthesized using a Witting reaction. Molecular orbital calculations will be performed to predict reactivity, infrared spectra, and optimized structure. The phosphoranylidene used will by synthesized by reacting 1-bromo-3,3-dimethyl-2-butanone with triphenylphosphine. Then the reactive sities will be tested using phenyllithium.","abstract_has_math":false,"creators":["Christie, Lance Christopher"],"institution":null,"degree_name":"Master of Science in Chemistry","degree_level":"Masters","degree_discipline":"Chemistry and Biochemistry","degree_department":null,"school":null,"contributors":["Tamera Jahnke"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1998,"date_issued":"1998-01-01T08:00:00Z","date_published":"1998-01-01T08:00:00Z","updated_at":"2026-07-24T03:15:23Z","subjects":["Chemistry"],"languages":[],"rights":["© Lance Christopher Christie"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://bearworks.missouristate.edu/theses/361","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Tamera Jahnke"]},{"key":"dc:creator","label":"Author","values":["Christie, Lance Christopher"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry and Biochemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science in Chemistry"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["© Lance Christopher Christie"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://bearworks.missouristate.edu/theses/361"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Hepoxilins are a group of compounds which are biologically active in the body. One of the hepoxilins is vital in the release of insulin. The sites that metabolism chemistry of the hepoxilin molecule takes place will be investigated using a model compound. The model compound, 4(E)-trans-6,7-epoxy-2,2-dimethly-4-decen-3-one, will be synthesized using a Witting reaction. Molecular orbital calculations will be performed to predict reactivity, infrared spectra, and optimized structure. The phosphoranylidene used will by synthesized by reacting 1-bromo-3,3-dimethyl-2-butanone with triphenylphosphine. Then the reactive sities will be tested using phenyllithium."]},{"key":"dc:title","label":"Title","values":["Study of 4(E)-Trans-6, 7-Epoxy-2, 2-Dimethyl-4-Decen-3-One"]}]}],"canonical_facts":{"dc:contributor":["Tamera Jahnke"],"dc:creator":["Christie, Lance Christopher"],"dc:description.abstract":["Hepoxilins are a group of compounds which are biologically active in the body. One of the hepoxilins is vital in the release of insulin. The sites that metabolism chemistry of the hepoxilin molecule takes place will be investigated using a model compound. The model compound, 4(E)-trans-6,7-epoxy-2,2-dimethly-4-decen-3-one, will be synthesized using a Witting reaction. Molecular orbital calculations will be performed to predict reactivity, infrared spectra, and optimized structure. The phosphoranylidene used will by synthesized by reacting 1-bromo-3,3-dimethyl-2-butanone with triphenylphosphine. Then the reactive sities will be tested using phenyllithium."],"dc:identifier":["https://bearworks.missouristate.edu/theses/361"],"dc:rights":["© Lance Christopher Christie"],"dc:subject":["Chemistry"],"dc:title":["Study of 4(E)-Trans-6, 7-Epoxy-2, 2-Dimethyl-4-Decen-3-One"],"thesis:degree_discipline":["Chemistry and Biochemistry"],"thesis:degree_level":["Masters"],"thesis:degree_name":["Master of Science in Chemistry"]},"updated_at":"2026-07-24T03:15:23Z"}