Fabrication and applications of in-fiber semiconductor and metal microspheres

Currently, the synthesis of semiconducting or metal microspheres has occurred via top-down approaches, such as through ball milling or e-beam lithography, or via bottom-up approaches, such as colloidal chemistry. Top-down approaches often generate a wide particle size distribution, while bottom up approaches often involve toxic and sometimes rather expensive precursors to generate the particles. By utilizing a phenomenon known as axial thermal capillary instability, highly homogeneous semiconducting and metal microspheres are able to be generated inside of a silica fiber in a simple, inexpensive, and non-toxic top-down approach. Further applications of these in-fiber microspheres, such as the band gap shift due to localized pressure on Germanium microspheres, and terahertz plasmonic resonances on Silver microspheres, were also studied.

Department dc:contributor.department

Massachusetts Institute of Technology. Department of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2015

Author dc:creator

• Sarathi, Tara

Advisor dc:contributor.advisor

• Yoel Fink.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/98315

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/98315