{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/97766"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/97766","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"Electrochemical modulation of fluorescence of nitrogen vacancy centers in nanodiamonds for voltage sensing applications","abstract":"The nitrogen vacancy (NV) color center in diamond has been used to sense environmental variables such as temperature and electric and magnetic fields. Most sensing protocols depend on the optically detectable magnetic resonance of the negatively charged NV- spin state. As such, fluctuations in the NV charge state present a challenge for NV- spin-based sensing. This thesis discusses the electrochemical modulation of NV charge state and fluorescence as the basis for an alternative sensing scheme. An externally applied electrochemical potential shifts the occupation probabilities of the NV in each charge state, which manifest as changes in NV fluorescence intensity and emission spectra. In this thesis, the voltage dependence of fluorescence in high pressure high temperature nanodiamonds is demonstrated in an electrochemical cell. Following this, the mechanisms for NV response to externally applied electrical bias are investigated in other electrochemical cell morphologies, capacitors, and interdigitated electrode arrays. Finally, a design of an optical microscope setup for future studies of NV sensing in nanodiamond is outlined.","abstract_html":"The nitrogen vacancy (NV) color center in diamond has been used to sense environmental variables such as temperature and electric and magnetic fields. Most sensing protocols depend on the optically detectable magnetic resonance of the negatively charged NV- spin state. As such, fluctuations in the NV charge state present a challenge for NV- spin-based sensing. This thesis discusses the electrochemical modulation of NV charge state and fluorescence as the basis for an alternative sensing scheme. An externally applied electrochemical potential shifts the occupation probabilities of the NV in each charge state, which manifest as changes in NV fluorescence intensity and emission spectra. In this thesis, the voltage dependence of fluorescence in high pressure high temperature nanodiamonds is demonstrated in an electrochemical cell. Following this, the mechanisms for NV response to externally applied electrical bias are investigated in other electrochemical cell morphologies, capacitors, and interdigitated electrode arrays. Finally, a design of an optical microscope setup for future studies of NV sensing in nanodiamond is outlined.","abstract_has_math":false,"creators":["Sakakibara, Reyu"],"institution":"Massachusetts Institute of Technology","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science.","school":null,"contributors":[],"advisors":["Dirk Englund."],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015","date_published":"2015","updated_at":"2026-07-22T22:21:09Z","subjects":["Electrical Engineering and Computer Science."],"languages":["eng"],"rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"rights_urls":["http://dspace.mit.edu/handle/1721.1/7582"],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/1721.1/97766","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Dirk Englund."]},{"key":"dc:contributor.department","label":"Department","values":["Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science."]},{"key":"dc:contributor.other","label":"Dc Contributor Other","values":["Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science."]},{"key":"dc:creator","label":"Author","values":["Sakakibara, Reyu"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2015-07-17T19:12:55Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2015-07-17T19:12:55Z"]},{"key":"dc:date.issued","label":"Date","values":["2015"]},{"key":"dc:publisher","label":"Institution","values":["Massachusetts Institute of Technology"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Electrical Engineering and Computer Science."]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://dspace.mit.edu/handle/1721.1/7582"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/1721.1/97766"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Thesis: S.M., Massachusetts Institute of Technology, Department of Electrical Engineering and Computer Science, 2015.","This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.","Cataloged from student-submitted PDF version of thesis.","Includes bibliographical references (pages 105-112)."]},{"key":"dc:description.abstract","label":"Abstract","values":["The nitrogen vacancy (NV) color center in diamond has been used to sense environmental variables such as temperature and electric and magnetic fields. Most sensing protocols depend on the optically detectable magnetic resonance of the negatively charged NV- spin state. As such, fluctuations in the NV charge state present a challenge for NV- spin-based sensing. This thesis discusses the electrochemical modulation of NV charge state and fluorescence as the basis for an alternative sensing scheme. An externally applied electrochemical potential shifts the occupation probabilities of the NV in each charge state, which manifest as changes in NV fluorescence intensity and emission spectra. In this thesis, the voltage dependence of fluorescence in high pressure high temperature nanodiamonds is demonstrated in an electrochemical cell. Following this, the mechanisms for NV response to externally applied electrical bias are investigated in other electrochemical cell morphologies, capacitors, and interdigitated electrode arrays. Finally, a design of an optical microscope setup for future studies of NV sensing in nanodiamond is outlined."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["S.M."]},{"key":"dc:title","label":"Title","values":["Electrochemical modulation of fluorescence of nitrogen vacancy centers in nanodiamonds for voltage sensing applications"]}]}],"canonical_facts":{"dc:contributor.advisor":["Dirk Englund."],"dc:contributor.department":["Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science."],"dc:contributor.other":["Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science."],"dc:creator":["Sakakibara, Reyu"],"dc:date.accessioned":["2015-07-17T19:12:55Z"],"dc:date.available":["2015-07-17T19:12:55Z"],"dc:date.issued":["2015"],"dc:description":["Thesis: S.M., Massachusetts Institute of Technology, Department of Electrical Engineering and Computer Science, 2015.","This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.","Cataloged from student-submitted PDF version of thesis.","Includes bibliographical references (pages 105-112)."],"dc:description.abstract":["The nitrogen vacancy (NV) color center in diamond has been used to sense environmental variables such as temperature and electric and magnetic fields. Most sensing protocols depend on the optically detectable magnetic resonance of the negatively charged NV- spin state. As such, fluctuations in the NV charge state present a challenge for NV- spin-based sensing. This thesis discusses the electrochemical modulation of NV charge state and fluorescence as the basis for an alternative sensing scheme. An externally applied electrochemical potential shifts the occupation probabilities of the NV in each charge state, which manifest as changes in NV fluorescence intensity and emission spectra. In this thesis, the voltage dependence of fluorescence in high pressure high temperature nanodiamonds is demonstrated in an electrochemical cell. Following this, the mechanisms for NV response to externally applied electrical bias are investigated in other electrochemical cell morphologies, capacitors, and interdigitated electrode arrays. Finally, a design of an optical microscope setup for future studies of NV sensing in nanodiamond is outlined."],"dc:description.degree":["S.M."],"dc:identifier.uri":["http://hdl.handle.net/1721.1/97766"],"dc:language.iso":["eng"],"dc:publisher":["Massachusetts Institute of Technology"],"dc:rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"dc:rights.uri":["http://dspace.mit.edu/handle/1721.1/7582"],"dc:subject":["Electrical Engineering and Computer Science."],"dc:title":["Electrochemical modulation of fluorescence of nitrogen vacancy centers in nanodiamonds for voltage sensing applications"],"dc:type":["Thesis"]},"updated_at":"2026-07-22T22:21:09Z"}