{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/9115"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/9115","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"Experimental and ab initio investigations into the fundamentals of corrosion, in the context of supercritical water oxidation systems","abstract":"Supercritical water oxidation (SCWO) is a process which runs at 250 bar and 400- 6000 C to effect rapid and complete destruction of aqueous organics. The SCWO process streams are very corrosive and pose a materials performance challenge to even noble metals and the most advanced alloys. Corrosion in chlorinated, acidic streams at transitional temperatures (100-400° C) in a Hastelloy C-276 tube is examined through post-failure analysis and controlled exposure experiments. Dealloying and intergranular corrosion were observed. Dealloying rate was found to be strongly correlated with temperature and dielectric constant. Intergranular corrosion behavior was found to be affected by the alloy hardness. In order to understand the fundamental chemistry of localized chloride-assisted corrosion initiation, a density-functional calculation of Cr20 3 was performed and validated against experimental data. The (0001) surface of a-Cr20 3 was computed and found to experience strong relaxations in the terminal oxygens. The surface was found to be susceptible to attack by electron-rich species; this might be defeated by p-doping the oxide. Further, the chemically relevant states at the surface assumed a ferromagnetic order. Effects of a variable dielectric medium upon the chemistry of the surface were assessed for the bare surface and adsorption of H and Cl.","abstract_html":"Supercritical water oxidation (SCWO) is a process which runs at 250 bar and 400- 6000 C to effect rapid and complete destruction of aqueous organics. The SCWO process streams are very corrosive and pose a materials performance challenge to even noble metals and the most advanced alloys. Corrosion in chlorinated, acidic streams at transitional temperatures (100-400° C) in a Hastelloy C-276 tube is examined through post-failure analysis and controlled exposure experiments. Dealloying and intergranular corrosion were observed. Dealloying rate was found to be strongly correlated with temperature and dielectric constant. Intergranular corrosion behavior was found to be affected by the alloy hardness. In order to understand the fundamental chemistry of localized chloride-assisted corrosion initiation, a density-functional calculation of Cr20 3 was performed and validated against experimental data. The (0001) surface of a-Cr20 3 was computed and found to experience strong relaxations in the terminal oxygens. The surface was found to be susceptible to attack by electron-rich species; this might be defeated by p-doping the oxide. Further, the chemically relevant states at the surface assumed a ferromagnetic order. Effects of a variable dielectric medium upon the chemistry of the surface were assessed for the bare surface and adsorption of H and Cl.","abstract_has_math":false,"creators":["Cline, Jason Alexander, 1971-"],"institution":"Massachusetts Institute of Technology","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Massachusetts Institute of Technology. Dept. of Chemical Engineering.","school":null,"contributors":[],"advisors":["Jefferson W. Tester and Ronald M. Latanision."],"committee_chairs":[],"committee_members":[],"year":2000,"date_issued":"2000","date_published":"2000","updated_at":"2026-07-22T22:21:51Z","subjects":["Chemical Engineering."],"languages":["eng"],"rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"rights_urls":["http://dspace.mit.edu/handle/1721.1/7582"],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/1721.1/9115","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Jefferson W. Tester and Ronald M. Latanision."]},{"key":"dc:contributor.department","label":"Department","values":["Massachusetts Institute of Technology. Dept. of Chemical Engineering."]},{"key":"dc:contributor.other","label":"Dc Contributor Other","values":["Massachusetts Institute of Technology. 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They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://dspace.mit.edu/handle/1721.1/7582"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/1721.1/9115"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 2000.","Includes bibliographical references (leaves 195-207)."]},{"key":"dc:description.abstract","label":"Abstract","values":["Supercritical water oxidation (SCWO) is a process which runs at 250 bar and 400- 6000 C to effect rapid and complete destruction of aqueous organics. The SCWO process streams are very corrosive and pose a materials performance challenge to even noble metals and the most advanced alloys. Corrosion in chlorinated, acidic streams at transitional temperatures (100-400° C) in a Hastelloy C-276 tube is examined through post-failure analysis and controlled exposure experiments. Dealloying and intergranular corrosion were observed. Dealloying rate was found to be strongly correlated with temperature and dielectric constant. Intergranular corrosion behavior was found to be affected by the alloy hardness. In order to understand the fundamental chemistry of localized chloride-assisted corrosion initiation, a density-functional calculation of Cr20 3 was performed and validated against experimental data. The (0001) surface of a-Cr20 3 was computed and found to experience strong relaxations in the terminal oxygens. The surface was found to be susceptible to attack by electron-rich species; this might be defeated by p-doping the oxide. Further, the chemically relevant states at the surface assumed a ferromagnetic order. Effects of a variable dielectric medium upon the chemistry of the surface were assessed for the bare surface and adsorption of H and Cl."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Ph.D."]},{"key":"dc:format.mimetype","label":"Dc Format Mimetype","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Experimental and ab initio investigations into the fundamentals of corrosion, in the context of supercritical water oxidation systems"]}]}],"canonical_facts":{"dc:contributor.advisor":["Jefferson W. Tester and Ronald M. Latanision."],"dc:contributor.department":["Massachusetts Institute of Technology. Dept. of Chemical Engineering."],"dc:contributor.other":["Massachusetts Institute of Technology. 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Dealloying rate was found to be strongly correlated with temperature and dielectric constant. Intergranular corrosion behavior was found to be affected by the alloy hardness. In order to understand the fundamental chemistry of localized chloride-assisted corrosion initiation, a density-functional calculation of Cr20 3 was performed and validated against experimental data. The (0001) surface of a-Cr20 3 was computed and found to experience strong relaxations in the terminal oxygens. The surface was found to be susceptible to attack by electron-rich species; this might be defeated by p-doping the oxide. Further, the chemically relevant states at the surface assumed a ferromagnetic order. Effects of a variable dielectric medium upon the chemistry of the surface were assessed for the bare surface and adsorption of H and Cl."],"dc:description.degree":["Ph.D."],"dc:format.mimetype":["application/pdf"],"dc:identifier.uri":["http://hdl.handle.net/1721.1/9115"],"dc:language.iso":["eng"],"dc:publisher":["Massachusetts Institute of Technology"],"dc:rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"dc:rights.uri":["http://dspace.mit.edu/handle/1721.1/7582"],"dc:subject":["Chemical Engineering."],"dc:title":["Experimental and ab initio investigations into the fundamentals of corrosion, in the context of supercritical water oxidation systems"],"dc:type":["Thesis"]},"updated_at":"2026-07-22T22:21:51Z"}