M13 virus/single-walled carbon nanotubes as a materials platform for energy devices and biomedical applications

Making nanocomposites from combinations of materials each with their own unique functional advantage can often solve issues that cannot be addressed when utilizing only one type of materials. Therefore, controlling nanosturucture and nanoarchitecture have become central issues in both high performance energy devices and nanobiomedical applications. Biological systems can provide precise control over materials interaction between peptides and other non-biological materials through biological molecular recognition, and the capability of modifying and controlling materials interaction through genetic engineering provides an attractive route to creating new nano-structured hybrid materials systems. In this thesis work, new approaches to effectively incorporate single-walled carbon nanotubes (SWNTs) into energy devices are presented. Genetically engineered M13 virus clones are developed to assemble SWNTs and technically important inorganic materials biomineralized on the protein surfaces of M13 virus to create hybrid nano-structured electrodes for high power Li+ ion batteries and highly efficient photovoltaic devices. Moreover, new imaging probes for molecularly targeted fluorescence imaging of tumors are developed by utilizing the highly bright and water-stable SWNTs and genetically modifiable M13 virus. The fundamental understanding and new approaches this work presents will provide new insight into designing materials for high performance energy devices and nanobiomedical applications.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2011

Author dc:creator

• Yi, Hyunjung

Advisor dc:contributor.advisor

• Angela M. Belcher.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/69672

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/69672