{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/68548"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/68548","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene","abstract":"The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me₃SnBr with DPB as a ligand in place of triphenylphosphine. 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