A nanochemomechanical investigation of carbonated cement paste

Concrete, and in particular its principal component, cement paste, has an interesting relation with carbon dioxide. Concrete is a carbon dioxide generator-- it is estimated that 5-10% of atmospheric CO₂ comes from this source. Carbon dioxide is a concrete corroder-- it can penetrate into the porous concrete structure and cause great physical and chemical changes. Finally, a new engineering direction suggests the use of concrete as a carbon sequesterer. Carbon sequestration is the technique of containing large quantities of carbon dioxide in the fashion of waste control. Given the escalating quantity of carbon dioxide in our atmosphere, this technology is gaining increasing attention and may be implemented in cement paste-lined, defunct oil wells. Such a setup involves an interface between cement paste and large quantities of CO₂, and corrosion of the cement paste is inevitable. This would make carbon sequestration the first technology to employ carbonated cement paste as a structural material and, as such, requires a well-developed knowledge of both the processes and the product. The goal of this thesis is an investigation of the fundamental properties of carbonated cement paste. For a set of class G oil well cement pastes carbonated under wet-supercritical CO₂ and CO₂-saturated water, we find that the fundamental building blocks of the carbonated material are calcium carbonate, decalcified C-S-H, and silica gel.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Civil and Environmental Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2009

Author dc:creator

• Vanzo, James (James F.)

Advisor dc:contributor.advisor

• Franz-Josef Ulm.

• Civil and Environmental Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/55260

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/55260