Abstract
dc:description.abstractGuiding electro-magnetic radiation is fundamental to optics. Lenses, mirrors, and photonic crystals all accomplish this task by different routes. Understanding the interaction of light with materials is fundamental to improving and extending optical science and engineering as well as producing novel optical elements. Improvement in this understanding should not only include work to understand the interaction with traditional engineering materials but also should target the understanding of the interaction of electromagnetic radiation with biological structures as millions of years of evolution have sorted out numerous ways to modulate light (e.g. the fish eye or the skin of the octopus). The goal of this thesis work is to fabricate novel optical elements by taking cues from nature and extending the state of the art in light guiding behavior. Here, optical elements are defined as structured materials that guide or direct electromagnetic radiation in a predetermined manner. The work presented in this thesis encompasses biologically inspired tunable multilayer reflectors made from block copolymers and improvements to liquid filled lenses which mimic the human eye.In this thesis a poly(styrene)-poly(2-vinylpyridine) block copolymer was used to create a bio-mimetic, one-dimensional, multilayer reflector. The wavelengths of light reflected from this multilayer reflector or Bragg stack were tuned by the application of stimuli which included temperature, change in the solvent environment, pH, salt concentration in the solvent, and electrochemistry.
Degree
thesis:*- Department dc:contributor.department
- Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.
- Grantor dc:publisher
- Massachusetts Institute of Technology
- Year dc:date.issued
- 2008
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Walish, Joseph John
- Advisor dc:contributor.advisor
-
- Edwin L. Thomas.
Subjects
dc:subject × 1Rights
dc:rights- Statement dc:rights
-
- M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.
- Licence dc:rights.uri
- Language dc:language.iso
- eng
Identifiers
dc:identifier.*- Handle dc:identifier.uri
- http://hdl.handle.net/1721.1/45950
- OAI identifier oai:identifier
- oai:dspace.mit.edu:1721.1/45950