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Massachusetts Institute of Technology

A constitutive theory for the mechanical response of amorphous metals at high temperatures spanning the glass transition temperature : application to microscale thermoplastic forming of Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀Be₂₂.₅

Abstract

dc:description.abstract

Bulk metallic glasses (BMGs) are a promising emerging engineering material distinguished by their unique mechanical properties and amorphous microstructure. In recent years, an extremely promising microscale processing method for bulk metallic glasses, called thermoplasticforming has emerged. As with any emerging technology, the scientific basis for this process is at present fragmented and limited. As a result their is no generally agreed upon theory to model the large-deformation, elastic-visco-plastic response of amorphous metals in the temperature range relevant to thermoplastic-forming. What is needed is a unified constitutive framework that is capable of capturing the transition from a elastic-visco-plastic solid-like response below the glass transition to a Newtonian fluid-like response above the glass transition. We have developed a finite-deformation constitutive theory aimed to fill this need. The material parameters appearing in the theory have been determined to reproduce the experimentally measured stress-strain response of Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀Be₂₂.₅ (Vitreloy-1) in a strain rate range of [10-5, 10-1] s-1, and in a temperature range [593, 683] K, which spans the glass transition temperature [nu]9 = 623K of this material. We have implemented our theory in the finite element program ABAQUS/Explicit. The numerical simulation capability of the theory is demonstrated with simulations of micron-scale hot-embossing processes for the manufacture of micro-patterned surfaces.

Degree

thesis:*
Department dc:contributor.department
Massachusetts Institute of Technology. Dept. of Mechanical Engineering.
Grantor dc:publisher
Massachusetts Institute of Technology
Year dc:date.issued
2008

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Henann, David Lee
Advisor dc:contributor.advisor
  • Lallit Anand.

Subjects

dc:subject × 1

Rights

dc:rights
Statement dc:rights
  • M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.
Language dc:language.iso
eng

Identifiers

dc:identifier.*
Handle dc:identifier.uri
http://hdl.handle.net/1721.1/44885
OAI identifier oai:identifier
oai:dspace.mit.edu:1721.1/44885

Chain of custody

source
Harvested from
MIT
Base URL
dspace.mit.edu/oai/request
Last updated
2026-07-22
Source record
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citation

Henann, David Lee. A constitutive theory for the mechanical response of amorphous metals at high temperatures spanning the glass transition temperature : application to microscale thermoplastic forming of Zr₄₁.₂Ti₁₃.₈Cu₁₂.₅Ni₁₀Be₂₂.₅. Massachusetts Institute of Technology, 2008. http://hdl.handle.net/1721.1/44885