{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/44457"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/44457","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"Templated self-assembly of sub-10 nm quantum dots","abstract":"Patterned templates can guide the self-assembly of nanoparticles into ordered arrays. Our motivation in pursuing templated self-assembly is to develop a robust method for the creation of ordered structures at length scales below ten nanometers. The basic process entails creating surface relief templates via electron-beam lithography, and spin-coating a suspension of colloidal nanoparticles onto the template. As the solvent evaporates, the quantum dots self-assemble primarily through the capillary forces created by the dewetting of the template. We demonstrate this technique at sub-10nm length scales by spin-coating a solution of organically-capped CdZnS semiconducting quantum dots onto nanopatterned grating structures on silicon substrates. We observe the geometric confinement of the quantum dots via physical templating and capillary forces into well-ordered monolayer aggregates with defined lattice orientations. While recent research has demonstrated the ability to self-assemble sub-10nm metallic nanoparticles via capillary forces into physical templates of similar size, this work is unique in the demonstration of lattice orientation control via physical templating at sub-10nm length scales.","abstract_html":"Patterned templates can guide the self-assembly of nanoparticles into ordered arrays. Our motivation in pursuing templated self-assembly is to develop a robust method for the creation of ordered structures at length scales below ten nanometers. The basic process entails creating surface relief templates via electron-beam lithography, and spin-coating a suspension of colloidal nanoparticles onto the template. As the solvent evaporates, the quantum dots self-assemble primarily through the capillary forces created by the dewetting of the template. We demonstrate this technique at sub-10nm length scales by spin-coating a solution of organically-capped CdZnS semiconducting quantum dots onto nanopatterned grating structures on silicon substrates. We observe the geometric confinement of the quantum dots via physical templating and capillary forces into well-ordered monolayer aggregates with defined lattice orientations. While recent research has demonstrated the ability to self-assemble sub-10nm metallic nanoparticles via capillary forces into physical templates of similar size, this work is unique in the demonstration of lattice orientation control via physical templating at sub-10nm length scales.","abstract_has_math":false,"creators":["Leu, Joshua C. (Joshua Chung)"],"institution":"Massachusetts Institute of Technology","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science.","school":null,"contributors":[],"advisors":["Karl K. Berggren."],"committee_chairs":[],"committee_members":[],"year":2008,"date_issued":"2008","date_published":"2008","updated_at":"2026-07-22T22:21:38Z","subjects":["Electrical Engineering and Computer Science."],"languages":["eng"],"rights":["M.I.T. theses are protected by copyright. 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Our motivation in pursuing templated self-assembly is to develop a robust method for the creation of ordered structures at length scales below ten nanometers. The basic process entails creating surface relief templates via electron-beam lithography, and spin-coating a suspension of colloidal nanoparticles onto the template. As the solvent evaporates, the quantum dots self-assemble primarily through the capillary forces created by the dewetting of the template. We demonstrate this technique at sub-10nm length scales by spin-coating a solution of organically-capped CdZnS semiconducting quantum dots onto nanopatterned grating structures on silicon substrates. We observe the geometric confinement of the quantum dots via physical templating and capillary forces into well-ordered monolayer aggregates with defined lattice orientations. While recent research has demonstrated the ability to self-assemble sub-10nm metallic nanoparticles via capillary forces into physical templates of similar size, this work is unique in the demonstration of lattice orientation control via physical templating at sub-10nm length scales."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["S.M."]},{"key":"dc:title","label":"Title","values":["Templated self-assembly of sub-10 nm quantum dots"]}]}],"canonical_facts":{"dc:contributor.advisor":["Karl K. Berggren."],"dc:contributor.department":["Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science."],"dc:contributor.other":["Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science."],"dc:creator":["Leu, Joshua C. 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We demonstrate this technique at sub-10nm length scales by spin-coating a solution of organically-capped CdZnS semiconducting quantum dots onto nanopatterned grating structures on silicon substrates. We observe the geometric confinement of the quantum dots via physical templating and capillary forces into well-ordered monolayer aggregates with defined lattice orientations. While recent research has demonstrated the ability to self-assemble sub-10nm metallic nanoparticles via capillary forces into physical templates of similar size, this work is unique in the demonstration of lattice orientation control via physical templating at sub-10nm length scales."],"dc:description.degree":["S.M."],"dc:identifier.uri":["http://hdl.handle.net/1721.1/44457"],"dc:language.iso":["eng"],"dc:publisher":["Massachusetts Institute of Technology"],"dc:rights":["M.I.T. theses are protected by copyright. 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