Ultra-lightweight nanorelief networks : photopatterned microframes

Lightweight nano-network structures in polymers have been fabricated and investigated for their mechanical properties. Fabrication techniques via holographic interference lithography and phase mask lithography were implemented for periodic and quasiperiodic bicontinuous polymer-air structures on the submicrometer length scale. For 3D quasiperiodically nanostructured materials, quasicrystalline phase mask lithography utilizing 2D quasiperiodic phase mask was successfully employed. 2D hexagonal arrays of air cylinders in SU8 polymer films and 3D four-beam connected (3- R3m ) and octagonal quasicrystalline SU8 films were fabricated and analyzed in this thesis. For investigating the mechanical properties of various nano-network structures, three different methods of mechanical characterization were applied. Atomic force microscopy with its nanometer scale resolution was adopted to conduct force measurements to probe local elastic properties of the sample. Templated by the light intensity distribution from three-beam interference, the spatial distribution of elastic modulus was observed in the pattern of 2D hexagonal air-cylinder and a uniform SU8 polymer film by AFM nanoindentation. A second method for mechanical characterization, the microtensile tester enabled us to evaluate a symmetry effect on the elastic and plastic properties of the polymer fibers and thin films. Large plastic deformation of 200nm-diameter struts comprising the 3D periodic and quasiperiodic microframes of the normal brittle bulk polymer was discovered and is an example of length-scale dependent mechanical behavior. Crack propagation and energy absorption were guided along the symmetry directions in the periodic structures. However, there was found no preferred direction of crack propagation in quasicrystalline nanostructures due to the absence of translational symmetry.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2007

Author dc:creator

• Choi, Taeyi

Advisor dc:contributor.advisor

• Edwin . Thomas.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/43220

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/43220