Charge-carrier transport in amorphous organic semiconductors

Since the first reports of efficient luminescence and absorption in organic semiconductors, organic light-emitting devices (OLEDs) and photovoltaics (OPVs) have attracted increasing interest. Organic semiconductors have proven to be a promising material set for novel optical and/or electrical devices. Not only do they have the advantage of tunable properties using chemistry, but organic semiconductors hold the potential of being fabricated cheaply with low temperature deposition on flexible plastic substrates, ink jet printing, or roll-to-roll manufacturing. These fabrication techniques are possible because organic semiconductors are composed of molecules weakly held together by van der Waals forces rather than covalent bonds. Van der Waals bonding eliminates the danger of dangling bond traps in amorphous or polycrystalline inorganic films, but results in narrower electronic bandwidths. Combined with spatial and energetic disorder due to weak intermolecular interactions, the small bandwidth leads to localization of charge carriers and electron-hole pairs, called excitons. Thus, the charge-carrier mobility in organic semiconductors is generally much smaller than in their covalently-bonded, highly-ordered crystalline semiconductor counterparts. Indeed, one major barrier to the use of organic semiconductors is their poor charge transport characteristics. Yet this major component of the operation of disordered organic semiconductor devices remains incompletely understood. This thesis analyzes charge transport and injection in organic semiconductor materials. A first-principles analytic theory that explains the current-voltage characteristics and charge-carrier mobility for different metal contacts and organic semiconductor materials over a wide range of temperatures, carrier densities, and electric field strengths will be developed.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2008

Author dc:creator

• Limketkai, Benjie, 1982-

Advisor dc:contributor.advisor

• Marc A. Baldo.

• Electrical Engineering and Computer Science.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/43063

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/43063