The design of a microfabricated air electrode for liquid electrolyte fuel cells

In this dissertation, the microfabricated electrode (MFE) concept was applied to the design of an air electrode for liquid electrolyte fuel cells. The catalyst layer of the electrode is envisioned to be fabricated by using a microfabricated die to apply a three-dimensionally patterned macro-texture upon a microporous carbon matrix. The resulting dual porosity structure consists of an array of cylindrical holes that are formed from the die and micropores present in the carbon matrix. The holes are used for gas transport while the micropores are saturated with a liquid electrolyte for ion transport. The catalyst is loaded into the microfabricated structure by electrodepositing thin catalyst films within the cylindrical holes. In this dissertation, three issues concerning the design of the MFE were investigated: 1) identification of the best material to use for the microporous carbon matrix, 2) the study of electrokinetic parameters of electrodeposited Pt films, and 3) the study of oxygen transport behavior within a Pt film supported on the surface of a microporous carbon matrix. Two types of polymer-bonded carbon materials have been identified as suitable materials for the carbon matrix. They are carbon black particles bonded into a microporous matrix either by polytetrafluoroethylene (PTFE) fibrils or by polyethersulfone (PES), which is a soluble polymer in common solvents. Experiments and modeling have indicated that these materials will allow the microfabricated catalyst layer to have an effective ionic conductivity that is 4 to 5 times greater than the conventional catalyst layer. Rotating disk electrode experiments on electrodeposited Pt films in 0.5 M sulfuric acid show that these films have an oxygen reduction reaction mass activity that is 2.5 times greater than that of Pt particles supported on carbon black.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Mechanical Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2007

Author dc:creator

• Pierre, Fritz, 1977-

Advisor dc:contributor.advisor

• Ernest Cravalho.

• Mechanical Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/42286

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/42286