Multifunctional systems with polymer actuators : mechanochromism and peristalic pumping

The mission of the ISN is to explore the long-range vision of the role of nanotechnology in the future of soldier protection. Unprecedented survivability will arise from the cohesive and comprehensive coordination of the functions and interactions of each technology. The present work approaches these objectives with basic research to support the development of two multifunctional soldier survivability systems, pumping microfibers and mechanochromic pixels. Progress was made along the two major paths of investigation towards the realization of a pumping microfiber. Polypyrrole was chemically deposited onto copolyetherester. Tubular polypyrrole actuators at the millimeter scale were electrochemically fabricated and actuated. Mechanochromic polymers can be combined with actuating polymers to create a color changing pixel. Reflectance spectrum changes with strain in mechanochromic materials were characterized. Several pixel designs were analyzed and tested in which the polymer actuator polypyrrole induces deformation of the mechanochromic block copolymer. Integrative studies inform the overall systems architecture of the far future battlesuit. Scoping calculations to investigate battlesuit functionality requirements were performed.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Mechanical Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2005

Author dc:creator

• Cromie, Melinda Joy

Advisor dc:contributor.advisor

• Edwin L. Thomas and William A. Peters.

• Mechanical Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/33902

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/33902