In-situ and ex-situ observations of lithium de-intercalation from LiCoO₂ : atomic force microscopy and transmission electron microscopy studies

Lithium cobalt dioxide is the most commonly used material for positive electrodes in lithium rechargeable batteries. During lithium de-intercalation from this material, ... undergoes a number of phase transitions, which have been studied by bulk techniques and first-principles calculations. The objective of this work was to examine the effect of charge and discharge on individual LiC₀O₂ crystals. Atomic Force Microscopy and Transmission Electron Microscopy were used to observe the effects of lithium ion de-intercalation from ... in individual crystals. This work was the first study to use in-situ Atomic Force Microscopy to probe the dynamic evolution of ... crystal morphology as lithium ions are de-intercalated from the material. The overall crystal morphology did not seem to evolve very much during the first charge and discharge cycle however evidence was found for expansion and contraction of crystal steps during cycling. The evolution of layer spacing was quantified from AFM data and was found to be in agreement with X-ray diffraction studies by other researchers. Furthermore, rounded bumps were observed on the surface of most of the crystals, and it is speculated that these bumps are Li₂CO₃ impurities, formed on the surface of LiC₀O₂ after storage in air. Lastly, the formation of a surface layer on ... crystals and the gold foil substrate was observed when the cell was over-discharged to approximately 2.5V. Transmission Electron Microscopy was used to image individual LixCoO2 crystals for different values of lithium concentration in the range corresponding to the insulator-metal phase transition.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Mechanical Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2005

Author dc:creator

• Clémençon, Anne

Advisor dc:contributor.advisor

• Yang Shao-Horn.

• Mechanical Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/32382

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/32382