Synthesis and characterization of nanocrystalline alloys in the binary Ni-Co system/

Nanocrystalline Ni-Co alloys were synthesized using pulsed electrodeposition from a Watts-type bath, and the various plating parameters were systematically varied to examine their effect on the composition, quality, and structure of the resulting deposits. Increasing the pH of the plating bath and/or the average plating current density increased the Ni content of the deposits, but both of these parameters exhibited rather narrow processing windows for the preparation of high-quality deposits. The addition of saccharin during plating was observed both to reduce the crystallographic texture of the Ni-Co alloys and to refine the grain structure. Owing to the low stacking fault energy of Co, many of the alloy deposits exhibited a large density of nanoscale twins. The unique dual-scale grain and nano-twin structure found here caused apparent discrepancies in the grain size measured by XRD and by other microscopy techniques, and also resulted in unique trends in hardness. This thesis lays the groundwork for future tailoring of nanostructured alloys to explore how twins and stacking faults influence their strength and ductility.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2004

Author dc:creator

• Wu, Bruce Y. C., 1980

Advisor dc:contributor.advisor

• Christopher A. Schuh.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/32269

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/32269