Pore-scale processes : quantification of the controls on the transport of Ra and Cr, and development of a novel geochemical visualization tool

Addressing soil contamination inorganic metals and metalloids remains a critical task for the continuing protection of human health globally. The dissolved concentrations of contaminants are controlled by a wide range of biogeochemical processes including oxidation and reduction by microbes, sorption to minerals and organic matter, and complexation with ligands in solution. Depending on the contaminant of interest, the importance of these different processes will widely vary, and the natural heterogeneity of soil systems all further frustrate modeling of contaminant transport. Recent studies have demonstrated that soil conditions vary at scales as small as individual soil pores, suggesting that the controls on contaminant transport also vary at that scale. Understanding the impact these pore scale processes have is necessary to build accurate conceptual models of contaminant fate. The work here explores these types of microscale processes through three different projects. The first project focuses on the sorption of radium, a naturally occurring radioactive material, to different minerals. Surface complexation modeling of Ra was able to replicate sorption experiments, but could not predict the impact of different solution conditions. The second project examines metal reduction via Fe (hyrd)-oxides, showing that bacteria may be able to form networks with semi-conducting Fe (hydr)-oxides. This means bacteria can access electron acceptors without physical contact, and will impact the cycling of redox sensitive metals at pore scales. The final project was the development in a microfluidic device that could be used to directly visualize biogeochemical processes at pore scales through x-ray fluorescence microprobe spectroscopy. The three projects, though focused on different systems, each reveal the importance of considering how microscale processes impact transport of contaminants.

Name thesis:degree_name

Doctoral

Department dc:contributor.department

Massachusetts Institute of Technology. Department of Civil and Environmental Engineering

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2019

Author dc:creator

• Chen, Michael Andrew.

Advisor dc:contributor.advisor

• Benjamin D. Kocar.

• Civil and Environmental Engineering.

Statement dc:rights

• MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

https://hdl.handle.net/1721.1/123225

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/123225