{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/117801"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/117801","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"Defects and charge-carrier lifetime in early-stage photovoltaic materials : relating experiment to theory","abstract":"To minimize risks associated with climate change, we must rapidly reduce greenhouse gas emissions worldwide by shifting reliance away from fossil fuels. Solar photovoltaic (PV) modules are well suited for reducing emissions; however, manufacturing and capital costs must continue to decline for rapid, worldwide PV adoption. Low-cost and Earth-abundant \"thin film\" materials offer potential in spurring PV growth, but their development is often hampered by the presence of defects, which degrade solar cell efficiency due to short charge-carrier lifetimes. In this thesis, such defects and their impact on lifetime in early-stage PV materials are investigated, focusing on experimental methods to assess lifetime connected to theoretical concepts about both defects and lifetime measurements themselves. First, time-resolved photoluminescence is performed, and both analytical and numerical modeling are used to determine lifetimes exceeding 1 nanosecond in six materials predicted to be \"defect tolerant.\" Two-photon spectroscopy is then employed to decrease the effect of surface recombination, enabling more representative estimates of \"bulk\" lifetime. Second, the role of impurities is explored by intentionally contaminating lead halide perovskites with iron. Synchrotron-based X-ray techniques are also utilized to investigate the distribution and charge state of incorporated iron, and perovskite solar cells are found to tolerate approximately 100 times more iron in the feedstock than comparable p-type silicon solar cells. In addition, improved methods for extracting lifetime from solar cell devices are explored. Quantum efficiency measurements are performed and modeled on tin monosulfide solar cells to verify that very short lifetimes (30-100 picoseconds) limit device performance. Furthermore, temperature- and illumination-dependent current-voltage measurements are performed and modeled in iron-contaminated silicon solar cells- and analyzed with the help of a Bayesian inference algorithm-to estimate the defect parameters that directly relate to lifetime. Collectively, these studies serve to provide a more robust framework for assessing and mitigating the presence of defects in early-stage PV materials, streamlining efforts to better optimize their photovoltaic performance.","abstract_html":"To minimize risks associated with climate change, we must rapidly reduce greenhouse gas emissions worldwide by shifting reliance away from fossil fuels. Solar photovoltaic (PV) modules are well suited for reducing emissions; however, manufacturing and capital costs must continue to decline for rapid, worldwide PV adoption. Low-cost and Earth-abundant "thin film" materials offer potential in spurring PV growth, but their development is often hampered by the presence of defects, which degrade solar cell efficiency due to short charge-carrier lifetimes. In this thesis, such defects and their impact on lifetime in early-stage PV materials are investigated, focusing on experimental methods to assess lifetime connected to theoretical concepts about both defects and lifetime measurements themselves. First, time-resolved photoluminescence is performed, and both analytical and numerical modeling are used to determine lifetimes exceeding 1 nanosecond in six materials predicted to be "defect tolerant." Two-photon spectroscopy is then employed to decrease the effect of surface recombination, enabling more representative estimates of "bulk" lifetime. Second, the role of impurities is explored by intentionally contaminating lead halide perovskites with iron. Synchrotron-based X-ray techniques are also utilized to investigate the distribution and charge state of incorporated iron, and perovskite solar cells are found to tolerate approximately 100 times more iron in the feedstock than comparable p-type silicon solar cells. In addition, improved methods for extracting lifetime from solar cell devices are explored. Quantum efficiency measurements are performed and modeled on tin monosulfide solar cells to verify that very short lifetimes (30-100 picoseconds) limit device performance. Furthermore, temperature- and illumination-dependent current-voltage measurements are performed and modeled in iron-contaminated silicon solar cells- and analyzed with the help of a Bayesian inference algorithm-to estimate the defect parameters that directly relate to lifetime. Collectively, these studies serve to provide a more robust framework for assessing and mitigating the presence of defects in early-stage PV materials, streamlining efforts to better optimize their photovoltaic performance.","abstract_has_math":false,"creators":["Poindexter, Jeremy Roger"],"institution":"Massachusetts Institute of Technology","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Massachusetts Institute of Technology. Department of Materials Science and Engineering.","school":null,"contributors":[],"advisors":["Tonio Buonassisi."],"committee_chairs":[],"committee_members":[],"year":2018,"date_issued":"2018","date_published":"2018","updated_at":"2026-07-22T22:21:32Z","subjects":["Materials Science and Engineering."],"languages":["eng"],"rights":["MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission."],"rights_urls":["http://dspace.mit.edu/handle/1721.1/7582"],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/1721.1/117801","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Tonio Buonassisi."]},{"key":"dc:contributor.department","label":"Department","values":["Massachusetts Institute of Technology. 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They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission."]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://dspace.mit.edu/handle/1721.1/7582"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/1721.1/117801"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2018.","This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.","Cataloged student-submitted from PDF version of thesis.","Includes bibliographical references (pages 171-187)."]},{"key":"dc:description.abstract","label":"Abstract","values":["To minimize risks associated with climate change, we must rapidly reduce greenhouse gas emissions worldwide by shifting reliance away from fossil fuels. Solar photovoltaic (PV) modules are well suited for reducing emissions; however, manufacturing and capital costs must continue to decline for rapid, worldwide PV adoption. Low-cost and Earth-abundant \"thin film\" materials offer potential in spurring PV growth, but their development is often hampered by the presence of defects, which degrade solar cell efficiency due to short charge-carrier lifetimes. In this thesis, such defects and their impact on lifetime in early-stage PV materials are investigated, focusing on experimental methods to assess lifetime connected to theoretical concepts about both defects and lifetime measurements themselves. First, time-resolved photoluminescence is performed, and both analytical and numerical modeling are used to determine lifetimes exceeding 1 nanosecond in six materials predicted to be \"defect tolerant.\" Two-photon spectroscopy is then employed to decrease the effect of surface recombination, enabling more representative estimates of \"bulk\" lifetime. Second, the role of impurities is explored by intentionally contaminating lead halide perovskites with iron. Synchrotron-based X-ray techniques are also utilized to investigate the distribution and charge state of incorporated iron, and perovskite solar cells are found to tolerate approximately 100 times more iron in the feedstock than comparable p-type silicon solar cells. In addition, improved methods for extracting lifetime from solar cell devices are explored. Quantum efficiency measurements are performed and modeled on tin monosulfide solar cells to verify that very short lifetimes (30-100 picoseconds) limit device performance. Furthermore, temperature- and illumination-dependent current-voltage measurements are performed and modeled in iron-contaminated silicon solar cells- and analyzed with the help of a Bayesian inference algorithm-to estimate the defect parameters that directly relate to lifetime. Collectively, these studies serve to provide a more robust framework for assessing and mitigating the presence of defects in early-stage PV materials, streamlining efforts to better optimize their photovoltaic performance."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Ph. D."]},{"key":"dc:title","label":"Title","values":["Defects and charge-carrier lifetime in early-stage photovoltaic materials : relating experiment to theory"]}]}],"canonical_facts":{"dc:contributor.advisor":["Tonio Buonassisi."],"dc:contributor.department":["Massachusetts Institute of Technology. Department of Materials Science and Engineering."],"dc:contributor.other":["Massachusetts Institute of Technology. Department of Materials Science and Engineering."],"dc:creator":["Poindexter, Jeremy Roger"],"dc:date.accessioned":["2018-09-17T14:50:13Z"],"dc:date.available":["2018-09-17T14:50:13Z"],"dc:date.issued":["2018"],"dc:description":["Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2018.","This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.","Cataloged student-submitted from PDF version of thesis.","Includes bibliographical references (pages 171-187)."],"dc:description.abstract":["To minimize risks associated with climate change, we must rapidly reduce greenhouse gas emissions worldwide by shifting reliance away from fossil fuels. Solar photovoltaic (PV) modules are well suited for reducing emissions; however, manufacturing and capital costs must continue to decline for rapid, worldwide PV adoption. Low-cost and Earth-abundant \"thin film\" materials offer potential in spurring PV growth, but their development is often hampered by the presence of defects, which degrade solar cell efficiency due to short charge-carrier lifetimes. In this thesis, such defects and their impact on lifetime in early-stage PV materials are investigated, focusing on experimental methods to assess lifetime connected to theoretical concepts about both defects and lifetime measurements themselves. First, time-resolved photoluminescence is performed, and both analytical and numerical modeling are used to determine lifetimes exceeding 1 nanosecond in six materials predicted to be \"defect tolerant.\" Two-photon spectroscopy is then employed to decrease the effect of surface recombination, enabling more representative estimates of \"bulk\" lifetime. Second, the role of impurities is explored by intentionally contaminating lead halide perovskites with iron. Synchrotron-based X-ray techniques are also utilized to investigate the distribution and charge state of incorporated iron, and perovskite solar cells are found to tolerate approximately 100 times more iron in the feedstock than comparable p-type silicon solar cells. In addition, improved methods for extracting lifetime from solar cell devices are explored. Quantum efficiency measurements are performed and modeled on tin monosulfide solar cells to verify that very short lifetimes (30-100 picoseconds) limit device performance. Furthermore, temperature- and illumination-dependent current-voltage measurements are performed and modeled in iron-contaminated silicon solar cells- and analyzed with the help of a Bayesian inference algorithm-to estimate the defect parameters that directly relate to lifetime. Collectively, these studies serve to provide a more robust framework for assessing and mitigating the presence of defects in early-stage PV materials, streamlining efforts to better optimize their photovoltaic performance."],"dc:description.degree":["Ph. D."],"dc:identifier.uri":["http://hdl.handle.net/1721.1/117801"],"dc:language.iso":["eng"],"dc:publisher":["Massachusetts Institute of Technology"],"dc:rights":["MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission."],"dc:rights.uri":["http://dspace.mit.edu/handle/1721.1/7582"],"dc:subject":["Materials Science and Engineering."],"dc:title":["Defects and charge-carrier lifetime in early-stage photovoltaic materials : relating experiment to theory"],"dc:type":["Thesis"]},"updated_at":"2026-07-22T22:21:32Z"}