Theory and modeling of field electron emission from low-dimensional electron systems

While experimentalists have succeeded in fabricating nanoscale field electron emitters in a variety of geometries and materials for use as electron sources in vacuum nanoelectronic devices, theory and modeling of field electron emission have not kept pace. Treatments of field emission which address individual deviations of real emitter properties from conventional Fowler-Nordheim (FN) theory, such as emission from semiconductors, highly-curved surfaces, or low-dimensional systems, have been developed, but none have sought to treat these properties coherently within a single framework. As a result, the work in this thesis develops a multidimensional, semiclassical framework for field emission, from which models for field emitters of any dimensionality, geometry, and material can be derived. The effects of quantum confinement and emitter tip geometry on the properties of emission were investigated by utilizing the framework to derive models for: i) a highly-curved, nanoscale, metal emitter tip; ii) a bulk silicon emitter with a surface quantum well formed due to electric field penetration and a mechanism that limits the maximum conduction band emitted current density (ECD) to the bulk flux density supply; and iii) a cylindrical silicon nanowire emitter. Results from a highly-curved, nanoscale, metal emitter tip reveal that despite signicant electron supply reductions as a result of quantum confinement, the emitted current density (ECD) increases as the emitter radius decreases due to the effects of electric field enhancement. Additionally, emitters with radii smaller than 5 nm exhibit a narrow total energy distribution and highly non-linear FN plots. Consistent with experimental observations, the saturation of the conduction band ECD in silicon emitters leads to the appearance of three distinct regions in FN plots, which signify conduction-band-dominated, valence-band-dominated, and transitional regimes of emission. Confinement of electrons to a nanowire emitter geometry further reduces the electron supply available for emission and, consequently, the conduction band saturation ECD. Overall, findings show that the dimensionality, geometry, and material of field emitters all play a critical role in field emission processes at the nanoscale. Accordingly, the semiclassical framework for field emission is intended to form a solid foundation upon which more complete models of emission can be developed.

Department dc:contributor.department

Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2018

Author dc:creator

• Patterson. Alex A. (Alex Andrew)

Advisor dc:contributor.advisor

• Akintunde I. Akinwande.

• Electrical Engineering and Computer Science.

Statement dc:rights

• MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/115640

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/115640