{"id":{"repo_id":"mit","oai_identifier":"oai:dspace.mit.edu:1721.1/105585"},"canonical_url":"https://search.dev.ndltd.org/etd/mit/oai:dspace.mit.edu:1721.1/105585","repository":{"repo_id":"mit","name":"MIT","base_url":"https://dspace.mit.edu/oai/request"},"display":{"title":"An electron microscopy study of continuous ordering and phase separation in iron-rich iron-aluminum alloys","abstract":"The discrepancy between two recent phase diagram determinations of the Fe-Al system is resolved experimentally. Both diagrams are correct, but-one is a metastable coherent phase diagram. The iron-aluminum system possesses a tricritical point where a line of [lambda]- transitions ends at a miscibility gap at about 23 atom percent aluminum and 615°C. Rules of general applicability governing phase separation within the miscibility gap are developed. Application of the rules to the iron-aluminum system results in detailed predictions about the mechanisms of decomposition and their sequences in this system. Electron microscopy is used to study the reactions experimentally and the results are in agreement with theoretical predictions.","abstract_html":"The discrepancy between two recent phase diagram determinations of the Fe-Al system is resolved experimentally. Both diagrams are correct, but-one is a metastable coherent phase diagram. The iron-aluminum system possesses a tricritical point where a line of [lambda]- transitions ends at a miscibility gap at about 23 atom percent aluminum and 615°C. Rules of general applicability governing phase separation within the miscibility gap are developed. Application of the rules to the iron-aluminum system results in detailed predictions about the mechanisms of decomposition and their sequences in this system. Electron microscopy is used to study the reactions experimentally and the results are in agreement with theoretical predictions.","abstract_has_math":false,"creators":["Allen, Samuel Miller"],"institution":"Massachusetts Institute of Technology","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Massachusetts Institute of Technology. Department of Materials Science and Engineering.","school":null,"contributors":[],"advisors":["J.W. Cahn."],"committee_chairs":[],"committee_members":[],"year":1975,"date_issued":"1975","date_published":"1975","updated_at":"2026-07-22T22:22:11Z","subjects":["Materials Science and Engineering."],"languages":["eng"],"rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"rights_urls":["http://dspace.mit.edu/handle/1721.1/7582"],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/1721.1/105585","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["J.W. Cahn."]},{"key":"dc:contributor.department","label":"Department","values":["Massachusetts Institute of Technology. Department of Materials Science and Engineering."]},{"key":"dc:contributor.other","label":"Dc Contributor Other","values":["Massachusetts Institute of Technology. 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They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."]},{"key":"dc:rights.uri","label":"Rights URI","values":["http://dspace.mit.edu/handle/1721.1/7582"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/1721.1/105585"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Thesis: Ph. D., Massachusetts Institute of Technology. Department of Materials Science and Engineering, 1975.","Vita.","Includes bibliographical references."]},{"key":"dc:description.abstract","label":"Abstract","values":["The discrepancy between two recent phase diagram determinations of the Fe-Al system is resolved experimentally. Both diagrams are correct, but-one is a metastable coherent phase diagram. The iron-aluminum system possesses a tricritical point where a line of [lambda]- transitions ends at a miscibility gap at about 23 atom percent aluminum and 615°C. Rules of general applicability governing phase separation within the miscibility gap are developed. Application of the rules to the iron-aluminum system results in detailed predictions about the mechanisms of decomposition and their sequences in this system. Electron microscopy is used to study the reactions experimentally and the results are in agreement with theoretical predictions."]},{"key":"dc:description.degree","label":"Dc Description Degree","values":["Ph. D."]},{"key":"dc:title","label":"Title","values":["An electron microscopy study of continuous ordering and phase separation in iron-rich iron-aluminum alloys"]}]}],"canonical_facts":{"dc:contributor.advisor":["J.W. Cahn."],"dc:contributor.department":["Massachusetts Institute of Technology. Department of Materials Science and Engineering."],"dc:contributor.other":["Massachusetts Institute of Technology. Department of Materials Science and Engineering."],"dc:creator":["Allen, Samuel Miller"],"dc:date.accessioned":["2016-12-05T19:53:47Z"],"dc:date.available":["2016-12-05T19:53:47Z"],"dc:date.issued":["1975"],"dc:description":["Thesis: Ph. D., Massachusetts Institute of Technology. Department of Materials Science and Engineering, 1975.","Vita.","Includes bibliographical references."],"dc:description.abstract":["The discrepancy between two recent phase diagram determinations of the Fe-Al system is resolved experimentally. Both diagrams are correct, but-one is a metastable coherent phase diagram. The iron-aluminum system possesses a tricritical point where a line of [lambda]- transitions ends at a miscibility gap at about 23 atom percent aluminum and 615°C. Rules of general applicability governing phase separation within the miscibility gap are developed. Application of the rules to the iron-aluminum system results in detailed predictions about the mechanisms of decomposition and their sequences in this system. Electron microscopy is used to study the reactions experimentally and the results are in agreement with theoretical predictions."],"dc:description.degree":["Ph. D."],"dc:identifier.uri":["http://hdl.handle.net/1721.1/105585"],"dc:language.iso":["eng"],"dc:publisher":["Massachusetts Institute of Technology"],"dc:rights":["M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission."],"dc:rights.uri":["http://dspace.mit.edu/handle/1721.1/7582"],"dc:subject":["Materials Science and Engineering."],"dc:title":["An electron microscopy study of continuous ordering and phase separation in iron-rich iron-aluminum alloys"],"dc:type":["Thesis"]},"updated_at":"2026-07-22T22:22:11Z"}