Oxidation & 1, 5-hydride shift of sulfoximine derivatives
type: CreativeWork
description: [ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI-COLUMBIA AT AUTHOR'S REQUEST.] Oxidation of N-alkyl and N-aryl sulfoximines and 1,5-hydride shift of S-alkenyl sulfoximines have been studied. Oxidation of N-alkyl sulfoximines using dimethyldioxirane gave sulfones and nitroso derivatives. A mechanism for the process was proposed. Thermal isomerization and decomposition of different N-substituted and S-alkenyl sulfoximines was studied. Cyclic sulfoximines and N-H sulfoximines were obtained. Reactivity was compared. Stereocenters and isomerization of cyclic products were studied. 1,5-Hydride shift was proposed as the mechanism for these transformations.
abstract: [ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI-COLUMBIA AT AUTHOR'S REQUEST.] Oxidation of N-alkyl and N-aryl sulfoximines and 1,5-hydride shift of S-alkenyl sulfoximines have been studied. Oxidation of N-alkyl sulfoximines using dimethyldioxirane gave sulfones and nitroso derivatives. A mechanism for the process was proposed. Thermal isomerization and decomposition of different N-substituted and S-alkenyl sulfoximines was studied. Cyclic sulfoximines and N-H sulfoximines were obtained. Reactivity was compared. Stereocenters and isomerization of cyclic products were studied. 1,5-Hydride shift was proposed as the mechanism for these transformations.
author: Gao, Xuefeng, 1980-
language: eng
language: English
date published: 2009
date modified: 2026-07-24T03:07:24Z
provider: University of Missouri
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Missouri--Columbia

PropertyValue
property ID: Handle
value: https://hdl.handle.net/10355/6646

PropertyValue
property ID: DOI
value: 10.32469/10355/6646