Copper (I) coordination networks synthesized with solid-solid reactions

The use of solid-solid reactions in the development of one-, two-, and three dimensional Cu(I) coordination networks are discussed. The solid-solid reactions were monitored by a variety of instrumental techniques to achieve a better picture of the solid-solid reaction mechanism. The crystalline reagents led to crystalline products with no amorphous phase. The nitrogen containing bridging ligands, 4,7-phenanthroline, 4,4'- dipyridyl, and trans-1,2-bis(4-pyridy1)ethylene in addition to 1,3-dithiane were used in the formation of these networks. The resultant crystalline compounds were compared to the solution-based products, showing that on average the same product was formed. Through the bridging ligands and a change in the coordinated solvent, the ultimate goal of showing how these solid-solid reactions could be expanded to cover a large array of reagents was accomplished.

Name thesis:degree_name

Ph. D.

Level thesis:degree_level

Doctoral

Discipline thesis:degree_discipline

Chemistry (MU)

Grantor dc:publisher

University of Missouri--Columbia

Year dc:date.issued

2008

Author dc:creator

• Bockhold, Steven

Advisor dc:contributor.advisor

• Keller, S. W. (Steven W.)

Statement dc:rights

• OpenAccess.

Language dc:language.iso

eng, English

DOI

https://doi.org/10.32469/10355/5612

OAI identifier oai:identifier

oai:mospace.umsystem.edu:10355/5612