{"id":{"repo_id":"mississippi","oai_identifier":"oai:egrove.olemiss.edu:etd-2543"},"canonical_url":"https://search.dev.ndltd.org/etd/mississippi/oai:egrove.olemiss.edu:etd-2543","repository":{"repo_id":"mississippi","name":"University of Mississippi","base_url":"https://egrove.olemiss.edu/do/oai/"},"display":{"title":"X-Ray Crystal Structure of Au36(SPh-pCH3)24 Nanomolecules","abstract":"Au36(SR)24 is one of the most comNanomolecules (NM) in gold NM field and crystal structures of Au36(SR)24 with different thiolate protecting ligand such as tert-butylbenzene thiol, thiophenol and cyclopentane thiol have been reported. It has been predicted that aromatic thiol protected Au36(SR)24 NM have same core structures like the other reported Au36(SR)24 NMs. Due to the steric and electronic conjugation effects the staples on the gold core exhibit minor changes in the bond length without affecting the gold core. By varying the Gold:Thiol ratio the NM size can be controlled. Herein, we report the synthesis, isolation and characterization of two new sizes in the p-MBT series and the crystal structure of Au36(SPh-pCH3)24 NM.","abstract_html":"Au36(SR)24 is one of the most comNanomolecules (NM) in gold NM field and crystal structures of Au36(SR)24 with different thiolate protecting ligand such as tert-butylbenzene thiol, thiophenol and cyclopentane thiol have been reported. It has been predicted that aromatic thiol protected Au36(SR)24 NM have same core structures like the other reported Au36(SR)24 NMs. Due to the steric and electronic conjugation effects the staples on the gold core exhibit minor changes in the bond length without affecting the gold core. By varying the Gold:Thiol ratio the NM size can be controlled. Herein, we report the synthesis, isolation and characterization of two new sizes in the p-MBT series and the crystal structure of Au36(SPh-pCH3)24 NM.","abstract_has_math":false,"creators":["Ganeshraj, Vigneshraja"],"institution":null,"degree_name":"M.S. in Chemistry","degree_level":"Thesis","degree_discipline":"Chemistry and Biochemistry","degree_department":null,"school":null,"contributors":["Amala Dass","Saumen Chakraborty","James Cizdziel"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2019,"date_issued":"2019-01-01T08:00:00Z","date_published":"2019-01-01T08:00:00Z","updated_at":"2026-07-24T03:07:00Z","subjects":["Inorganic Chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://egrove.olemiss.edu/etd/1544","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Amala Dass","Saumen Chakraborty","James Cizdziel"]},{"key":"dc:creator","label":"Author","values":["Ganeshraj, Vigneshraja"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2021-09-22T07:00:00Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry and Biochemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.S. in Chemistry"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Inorganic Chemistry"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://egrove.olemiss.edu/etd/1544"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Au36(SR)24 is one of the most comNanomolecules (NM) in gold NM field and crystal structures of Au36(SR)24 with different thiolate protecting ligand such as tert-butylbenzene thiol, thiophenol and cyclopentane thiol have been reported. It has been predicted that aromatic thiol protected Au36(SR)24 NM have same core structures like the other reported Au36(SR)24 NMs. Due to the steric and electronic conjugation effects the staples on the gold core exhibit minor changes in the bond length without affecting the gold core. By varying the Gold:Thiol ratio the NM size can be controlled. Herein, we report the synthesis, isolation and characterization of two new sizes in the p-MBT series and the crystal structure of Au36(SPh-pCH3)24 NM."]},{"key":"dc:title","label":"Title","values":["X-Ray Crystal Structure of Au36(SPh-pCH3)24 Nanomolecules"]}]}],"canonical_facts":{"dc:contributor":["Amala Dass","Saumen Chakraborty","James Cizdziel"],"dc:creator":["Ganeshraj, Vigneshraja"],"dc:date.available":["2021-09-22T07:00:00Z"],"dc:description.abstract":["Au36(SR)24 is one of the most comNanomolecules (NM) in gold NM field and crystal structures of Au36(SR)24 with different thiolate protecting ligand such as tert-butylbenzene thiol, thiophenol and cyclopentane thiol have been reported. It has been predicted that aromatic thiol protected Au36(SR)24 NM have same core structures like the other reported Au36(SR)24 NMs. Due to the steric and electronic conjugation effects the staples on the gold core exhibit minor changes in the bond length without affecting the gold core. By varying the Gold:Thiol ratio the NM size can be controlled. Herein, we report the synthesis, isolation and characterization of two new sizes in the p-MBT series and the crystal structure of Au36(SPh-pCH3)24 NM."],"dc:identifier":["https://egrove.olemiss.edu/etd/1544"],"dc:subject":["Inorganic Chemistry"],"dc:title":["X-Ray Crystal Structure of Au36(SPh-pCH3)24 Nanomolecules"],"thesis:degree_discipline":["Chemistry and Biochemistry"],"thesis:degree_level":["Thesis"],"thesis:degree_name":["M.S. in Chemistry"]},"updated_at":"2026-07-24T03:07:00Z"}