{"id":{"repo_id":"london-metro","oai_identifier":"oai:repository.londonmet.ac.uk:3369"},"canonical_url":"https://search.dev.ndltd.org/etd/london-metro/oai:repository.londonmet.ac.uk:3369","repository":{"repo_id":"london-metro","name":"London Metropolitan University","base_url":"https://repository.londonmet.ac.uk/cgi/oai2"},"display":{"title":"Photoinitiated coupling of dienes and monoolefins with pentacarbonyliron","abstract":"The photoreaction of pentacarbonyliron with 1,3-diene/monoolefin mixtures results in C-C coupling of the two organic substrates, forming a six-carbon chain which is coordinated to the Fe (CO) 3 moiety in a 1-a,4-6-n3 fashion. Using various 1,3- dienes and monoolefins carrying methyl and carboalkoxy substituents, the wide applicability of this process is demonstrated.","abstract_html":"The photoreaction of pentacarbonyliron with 1,3-diene/monoolefin mixtures results in C-C coupling of the two organic substrates, forming a six-carbon chain which is coordinated to the Fe (CO) 3 moiety in a 1-a,4-6-n3 fashion. Using various 1,3- dienes and monoolefins carrying methyl and carboalkoxy substituents, the wide applicability of this process is demonstrated.","abstract_has_math":false,"creators":["Salama, Ibrahim Hamed Ibrahim"],"institution":"Polytechnic of North London","degree_name":"phd","degree_level":"doctoral","degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1984,"date_issued":"1984-09","date_published":"1984-09","updated_at":"2026-07-24T02:54:30Z","subjects":["540 Chemistry & allied sciences"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier.grantnumber","label":"Dc Identifier Grantnumber","values":["N/A"],"render_values":[{"text":"N/A","href":null,"code":true}]}]},"links":{"outbound_url":null,"outbound_label":null,"outbound_source":null},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.sponsor","label":"Sponsor","values":["London Metropolitan University"]},{"key":"dc:creator","label":"Author","values":["Salama, Ibrahim Hamed Ibrahim"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1984-09"]},{"key":"dc:date.issued","label":"Date","values":["1984-09"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["School of Human Sciences (SHSC)","Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["Polytechnic of North London"]},{"key":"dc:relation.isreferencedby","label":"Dc Relation Isreferencedby","values":["https://repository.londonmet.ac.uk/3369/"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["phd"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["540 Chemistry & allied sciences"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.grantnumber","label":"Dc Identifier Grantnumber","values":["N/A"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://repository.londonmet.ac.uk/3369/1/349696.pdf"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The photoreaction of pentacarbonyliron with 1,3-diene/monoolefin mixtures results in C-C coupling of the two organic substrates, forming a six-carbon chain which is coordinated to the Fe (CO) 3 moiety in a 1-a,4-6-n3 fashion. Using various 1,3- dienes and monoolefins carrying methyl and carboalkoxy substituents, the wide applicability of this process is demonstrated."]},{"key":"dc:format","label":"Dc Format","values":["text"]},{"key":"dc:title","label":"Title","values":["Photoinitiated coupling of dienes and monoolefins with pentacarbonyliron"]}]}],"canonical_facts":{"dc:contributor.sponsor":["London Metropolitan University"],"dc:creator":["Salama, Ibrahim Hamed Ibrahim"],"dc:date":["1984-09"],"dc:date.issued":["1984-09"],"dc:description.abstract":["The photoreaction of pentacarbonyliron with 1,3-diene/monoolefin mixtures results in C-C coupling of the two organic substrates, forming a six-carbon chain which is coordinated to the Fe (CO) 3 moiety in a 1-a,4-6-n3 fashion. 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