Molekulare Dissoziation im elektronischen Grundzustand induziert durch Femtosekundenpulse im mittleren Infrarot

This work investigates the possibilities of ground-state chemistry by exciting molecular vibrations with femtosecond pulses in the mid-infrared. Vibrational ladder-climbing to high excitation levels (v=7-8) provides the necessary energy for bond scission. This excitation scheme was demonstrated with metal carbonyls and diazomethane. Only ultrashort laser pulses allow for excitation and subsequent reaction on a time scale faster than the statistical energy redistribution (IVR).

Level thesis:degree_level

thesis.doctoral

Grantor dc:publisher

Ludwig-Maximilians-Universität

Year

2003

Author dc:creator

• Windhorn, Lars

Repository record source_url

https://edoc.ub.uni-muenchen.de/1215/

OAI identifier oai:identifier

oai:edoc.ub.uni-muenchen.de:1215