{"id":{"repo_id":"liege","oai_identifier":"oai:orbi.ulg.ac.be:2268/38305"},"canonical_url":"https://search.dev.ndltd.org/etd/liege/oai:orbi.ulg.ac.be:2268/38305","repository":{"repo_id":"liege","name":"Université de Liège","base_url":"https://orbi.uliege.be/oai/request"},"display":{"title":"La spectroscopie des complexes de transfert de charge peut contribuer à l'interprétation du premier potentiel d'ionisation du donneur (éthylenimine, oxyde d'éthylene, sulfure d'éthylene)","abstract":"The relationships between the ionization energy (IE) of a donor compound and the position of the UV photoabsorption band of the complex of this donor with iodine as an acceptor are carefully analyzed. Their specificity with respect to (i) the adiabatic and vertical IE and (ii) the nature of the ionized orbital (n or pi) is examined. This analysis allowed us to attempt to determine the nature of the molecular orbital (MO) involved in the ionization process of ethylenimine, ethylene oxide and ethylene sulfide. Very likely the first IE corresponds to the ionization of the non-bonding (n) orbital located on the N and O atoms. Owing to the closeness of the \"n\" and \"pi\" IE for sulfides, in the case of ethylene sulfide no conclusion could be drawn.","abstract_html":"The relationships between the ionization energy (IE) of a donor compound and the position of the UV photoabsorption band of the complex of this donor with iodine as an acceptor are carefully analyzed. Their specificity with respect to (i) the adiabatic and vertical IE and (ii) the nature of the ionized orbital (n or pi) is examined. This analysis allowed us to attempt to determine the nature of the molecular orbital (MO) involved in the ionization process of ethylenimine, ethylene oxide and ethylene sulfide. Very likely the first IE corresponds to the ionization of the non-bonding (n) orbital located on the N and O atoms. Owing to the closeness of the "n" and "pi" IE for sulfides, in the case of ethylene sulfide no conclusion could be drawn.","abstract_has_math":false,"creators":["Locht, Robert"],"institution":"ULiège - Université de Liège","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["D'Or, L.","Momigny, J.","Laboratoire des Etats Ionisés."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1971,"date_issued":"1971-04-23","date_published":"1971-04-23","updated_at":"2026-07-24T02:49:27Z","subjects":["Visible/UV spectroscopy","Charge transfer","Iodine","Ethylenimine","Ethylene Oxide","Ethylene Sulfide","Ionization Potential","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"],"languages":["fr"],"rights":["open access","info:eu-repo/semantics/openAccess"],"rights_urls":["http://purl.org/coar/access_right/c_abf2"],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["info:hdl:2268/38305"],"render_values":[{"text":"info:hdl:2268/38305","href":null,"code":true}]}]},"links":{"outbound_url":"https://orbi.uliege.be/handle/2268/38305","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["D'Or, L.","Momigny, J.","Laboratoire des Etats Ionisés."]},{"key":"dc:creator","label":"Author","values":["Locht, Robert"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1971-04-23"]},{"key":"dc:publisher","label":"Institution","values":["ULiège - Université de Liège"]},{"key":"dc:type","label":"Dc Type","values":["doctoral thesis","http://purl.org/coar/resource_type/c_db06","info:eu-repo/semantics/doctoralThesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Visible/UV spectroscopy","Charge transfer","Iodine","Ethylenimine","Ethylene Oxide","Ethylene Sulfide","Ionization Potential","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["fr"]},{"key":"dc:rights","label":"Dc Rights","values":["open access","http://purl.org/coar/access_right/c_abf2","info:eu-repo/semantics/openAccess"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://orbi.uliege.be/handle/2268/38305","info:hdl:2268/38305","https://orbi.uliege.be/bitstream/2268/38305/1/LOCHT_1971_AnnThPhD.pdf"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The relationships between the ionization energy (IE) of a donor compound and the position of the UV photoabsorption band of the complex of this donor with iodine as an acceptor are carefully analyzed. Their specificity with respect to (i) the adiabatic and vertical IE and (ii) the nature of the ionized orbital (n or pi) is examined. This analysis allowed us to attempt to determine the nature of the molecular orbital (MO) involved in the ionization process of ethylenimine, ethylene oxide and ethylene sulfide. Very likely the first IE corresponds to the ionization of the non-bonding (n) orbital located on the N and O atoms. Owing to the closeness of the \"n\" and \"pi\" IE for sulfides, in the case of ethylene sulfide no conclusion could be drawn."]},{"key":"dc:format","label":"Dc Format","values":["44"]},{"key":"dc:title","label":"Title","values":["La spectroscopie des complexes de transfert de charge peut contribuer à l'interprétation du premier potentiel d'ionisation du donneur (éthylenimine, oxyde d'éthylene, sulfure d'éthylene)","The spectroscopy of charge transfer complexes can contribute to the interpretation of the first ionization potential of the donor (ethylenimine, ethylene oxide and ethylene sulfide)"]}]}],"canonical_facts":{"dc:contributor":["D'Or, L.","Momigny, J.","Laboratoire des Etats Ionisés."],"dc:creator":["Locht, Robert"],"dc:date":["1971-04-23"],"dc:description":["The relationships between the ionization energy (IE) of a donor compound and the position of the UV photoabsorption band of the complex of this donor with iodine as an acceptor are carefully analyzed. Their specificity with respect to (i) the adiabatic and vertical IE and (ii) the nature of the ionized orbital (n or pi) is examined. This analysis allowed us to attempt to determine the nature of the molecular orbital (MO) involved in the ionization process of ethylenimine, ethylene oxide and ethylene sulfide. Very likely the first IE corresponds to the ionization of the non-bonding (n) orbital located on the N and O atoms. Owing to the closeness of the \"n\" and \"pi\" IE for sulfides, in the case of ethylene sulfide no conclusion could be drawn."],"dc:format":["44"],"dc:identifier":["https://orbi.uliege.be/handle/2268/38305","info:hdl:2268/38305","https://orbi.uliege.be/bitstream/2268/38305/1/LOCHT_1971_AnnThPhD.pdf"],"dc:language":["fr"],"dc:publisher":["ULiège - Université de Liège"],"dc:rights":["open access","http://purl.org/coar/access_right/c_abf2","info:eu-repo/semantics/openAccess"],"dc:subject":["Visible/UV spectroscopy","Charge transfer","Iodine","Ethylenimine","Ethylene Oxide","Ethylene Sulfide","Ionization Potential","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"],"dc:title":["La spectroscopie des complexes de transfert de charge peut contribuer à l'interprétation du premier potentiel d'ionisation du donneur (éthylenimine, oxyde d'éthylene, sulfure d'éthylene)","The spectroscopy of charge transfer complexes can contribute to the interpretation of the first ionization potential of the donor (ethylenimine, ethylene oxide and ethylene sulfide)"],"dc:type":["doctoral thesis","http://purl.org/coar/resource_type/c_db06","info:eu-repo/semantics/doctoralThesis"]},"updated_at":"2026-07-24T02:49:27Z"}