{"id":{"repo_id":"liege","oai_identifier":"oai:orbi.ulg.ac.be:2268/174202"},"canonical_url":"https://search.dev.ndltd.org/etd/liege/oai:orbi.ulg.ac.be:2268/174202","repository":{"repo_id":"liege","name":"Université de Liège","base_url":"https://orbi.uliege.be/oai/request"},"display":{"title":"Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization","abstract":"The studies presented in this thesis aim to copolymerize ԑ-caprolactam (CL) with different derivatives of α-amino-ԑ-caprolactam (which has a functionalizable primary amine) via anionic ring-opening polymerization. By using this strategy, we describe: (i) the synthesis of thermally more stable fluorinated polyamide 6 having a hydrophobic surface; (ii) the synthesis of polyamides 6 bearing pendant cinnamoyl groups, which are thermo- and photoresponsivechromophore groups, and demonstrating their reversible crosslinking as well as improved thermo-mechanical properties; (iii) the copolymerization ofCL with a crosslinker (N-functionalized α-amino-ԑ-caprolactambis-monomers) into crosslinked polyamides 6.As part of our continuing interest in polyamide 6 chemistry, we developed the combination of anionic ring-opening polymerization of CL and chain-growth condensation polymerization of ethyl 4-butylaminobenzoate in order to obtain aliphatic/aromatic polyamides in one-step.","abstract_html":"The studies presented in this thesis aim to copolymerize ԑ-caprolactam (CL) with different derivatives of α-amino-ԑ-caprolactam (which has a functionalizable primary amine) via anionic ring-opening polymerization. By using this strategy, we describe: (i) the synthesis of thermally more stable fluorinated polyamide 6 having a hydrophobic surface; (ii) the synthesis of polyamides 6 bearing pendant cinnamoyl groups, which are thermo- and photoresponsivechromophore groups, and demonstrating their reversible crosslinking as well as improved thermo-mechanical properties; (iii) the copolymerization ofCL with a crosslinker (N-functionalized α-amino-ԑ-caprolactambis-monomers) into crosslinked polyamides 6.As part of our continuing interest in polyamide 6 chemistry, we developed the combination of anionic ring-opening polymerization of CL and chain-growth condensation polymerization of ethyl 4-butylaminobenzoate in order to obtain aliphatic/aromatic polyamides in one-step.","abstract_has_math":false,"creators":["Tunc, Deniz"],"institution":"ULiège - Université de Liège","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["Carlotti, Stephane","Lecomte, Philippe","LCPO (laboratoire de chimie des polymères organiques) and CERM (center for education and research on macromolecules)"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2014,"date_issued":"2014-10-30","date_published":"2014-10-30","updated_at":"2026-07-24T02:49:27Z","subjects":["polyamide 6","anionic ring opening polymerization","caprolactam","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"],"languages":["en"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["info:hdl:2268/174202"],"render_values":[{"text":"info:hdl:2268/174202","href":null,"code":true}]}]},"links":{"outbound_url":"https://orbi.uliege.be/handle/2268/174202","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Carlotti, Stephane","Lecomte, Philippe","LCPO (laboratoire de chimie des polymères organiques) and CERM (center for education and research on macromolecules)"]},{"key":"dc:creator","label":"Author","values":["Tunc, Deniz"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2014-10-30"]},{"key":"dc:publisher","label":"Institution","values":["ULiège - Université de Liège","Université de Bordeaux"]},{"key":"dc:type","label":"Dc Type","values":["doctoral thesis","http://purl.org/coar/resource_type/c_db06","info:eu-repo/semantics/doctoralThesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["polyamide 6","anionic ring opening polymerization","caprolactam","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["en"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://orbi.uliege.be/handle/2268/174202","info:hdl:2268/174202"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The studies presented in this thesis aim to copolymerize ԑ-caprolactam (CL) with different derivatives of α-amino-ԑ-caprolactam (which has a functionalizable primary amine) via anionic ring-opening polymerization. By using this strategy, we describe: (i) the synthesis of thermally more stable fluorinated polyamide 6 having a hydrophobic surface; (ii) the synthesis of polyamides 6 bearing pendant cinnamoyl groups, which are thermo- and photoresponsivechromophore groups, and demonstrating their reversible crosslinking as well as improved thermo-mechanical properties; (iii) the copolymerization ofCL with a crosslinker (N-functionalized α-amino-ԑ-caprolactambis-monomers) into crosslinked polyamides 6.As part of our continuing interest in polyamide 6 chemistry, we developed the combination of anionic ring-opening polymerization of CL and chain-growth condensation polymerization of ethyl 4-butylaminobenzoate in order to obtain aliphatic/aromatic polyamides in one-step.","Design and development of new polyamides by ring-opening polymerization for high performance composites materials"]},{"key":"dc:format","label":"Dc Format","values":["227"]},{"key":"dc:title","label":"Title","values":["Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization","Synthèse de polyamide 6 fonctionnalisés par polymérisation anionique par ouverture de cycle"]}]}],"canonical_facts":{"dc:contributor":["Carlotti, Stephane","Lecomte, Philippe","LCPO (laboratoire de chimie des polymères organiques) and CERM (center for education and research on macromolecules)"],"dc:creator":["Tunc, Deniz"],"dc:date":["2014-10-30"],"dc:description":["The studies presented in this thesis aim to copolymerize ԑ-caprolactam (CL) with different derivatives of α-amino-ԑ-caprolactam (which has a functionalizable primary amine) via anionic ring-opening polymerization. By using this strategy, we describe: (i) the synthesis of thermally more stable fluorinated polyamide 6 having a hydrophobic surface; (ii) the synthesis of polyamides 6 bearing pendant cinnamoyl groups, which are thermo- and photoresponsivechromophore groups, and demonstrating their reversible crosslinking as well as improved thermo-mechanical properties; (iii) the copolymerization ofCL with a crosslinker (N-functionalized α-amino-ԑ-caprolactambis-monomers) into crosslinked polyamides 6.As part of our continuing interest in polyamide 6 chemistry, we developed the combination of anionic ring-opening polymerization of CL and chain-growth condensation polymerization of ethyl 4-butylaminobenzoate in order to obtain aliphatic/aromatic polyamides in one-step.","Design and development of new polyamides by ring-opening polymerization for high performance composites materials"],"dc:format":["227"],"dc:identifier":["https://orbi.uliege.be/handle/2268/174202","info:hdl:2268/174202"],"dc:language":["en"],"dc:publisher":["ULiège - Université de Liège","Université de Bordeaux"],"dc:subject":["polyamide 6","anionic ring opening polymerization","caprolactam","Physical, chemical, mathematical & earth Sciences","Chemistry","Physique, chimie, mathématiques & sciences de la terre","Chimie"],"dc:title":["Synthesis of functionalized polyamide 6 by anionic ring-opening polymerization","Synthèse de polyamide 6 fonctionnalisés par polymérisation anionique par ouverture de cycle"],"dc:type":["doctoral thesis","http://purl.org/coar/resource_type/c_db06","info:eu-repo/semantics/doctoralThesis"]},"updated_at":"2026-07-24T02:49:27Z"}